Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Trimethylammonium Dichlorohexachlorotellurate(IV): Crystal Structure and Specific Features of Noncovalent Cl···Cl Interactions. / Usol’tsev, A. N.; Sonina, A. A.; Korobeinikov, N. A. и др.
в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 49, № 12, 12.2023, стр. 807-811.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Trimethylammonium Dichlorohexachlorotellurate(IV): Crystal Structure and Specific Features of Noncovalent Cl···Cl Interactions
AU - Usol’tsev, A. N.
AU - Sonina, A. A.
AU - Korobeinikov, N. A.
AU - Adonin, S. A.
N1 - This work was supported by the Russian Science Foundation (project no. 18-73-10040) and the Ministry of Science and Higher Education of the Russian Federation (structural characterization of the samples, project no. 121031700313-8). The authors are grateful to the Center for Collective Use of the Nikolaev Institute of Inorganic Chemistry (Siberian Branch, Russian Academy of Sciences) for a possibility of obtaining the initial XRD data. Публикация для корректировки.
PY - 2023/12
Y1 - 2023/12
N2 - The reaction of tellurium(IV) oxide with trimethylammonium chloride in the presence of gaseous chlorine in concentrated hydrochloric acid gives supramolecular dichlorohexachlorotellurate (Me3NH)2{[TeCl6](Cl2)} (I), whose structure is determined by X-ray diffraction (XRD) (CIF file CCDC no. 2217752). The data of elemental and XRD analyses suggest a restricted stability of the synthesized compound. Specific features of noncovalent Cl···Cl interactions in the crystal structure of compound I are studied by Raman spectroscopy.
AB - The reaction of tellurium(IV) oxide with trimethylammonium chloride in the presence of gaseous chlorine in concentrated hydrochloric acid gives supramolecular dichlorohexachlorotellurate (Me3NH)2{[TeCl6](Cl2)} (I), whose structure is determined by X-ray diffraction (XRD) (CIF file CCDC no. 2217752). The data of elemental and XRD analyses suggest a restricted stability of the synthesized compound. Specific features of noncovalent Cl···Cl interactions in the crystal structure of compound I are studied by Raman spectroscopy.
KW - XRD
KW - halide complexes
KW - halogen bond
KW - noncovalent interactions
KW - tellurium
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85180124446&origin=inward&txGid=2eea75f2039ac7b8c0e697da37ca5aff
UR - https://www.mendeley.com/catalogue/c988117f-c211-35f9-9f88-54ee5f33fb79/
U2 - 10.1134/S1070328423600213
DO - 10.1134/S1070328423600213
M3 - Article
VL - 49
SP - 807
EP - 811
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 12
ER -
ID: 59546126