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Trimethylammonium Dichlorohexachlorotellurate(IV): Crystal Structure and Specific Features of Noncovalent Cl···Cl Interactions. / Usol’tsev, A. N.; Sonina, A. A.; Korobeinikov, N. A. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 49, No. 12, 12.2023, p. 807-811.

Research output: Contribution to journalArticlepeer-review

Harvard

Usol’tsev, AN, Sonina, AA, Korobeinikov, NA & Adonin, SA 2023, 'Trimethylammonium Dichlorohexachlorotellurate(IV): Crystal Structure and Specific Features of Noncovalent Cl···Cl Interactions', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 49, no. 12, pp. 807-811. https://doi.org/10.1134/S1070328423600213

APA

Usol’tsev, A. N., Sonina, A. A., Korobeinikov, N. A., & Adonin, S. A. (2023). Trimethylammonium Dichlorohexachlorotellurate(IV): Crystal Structure and Specific Features of Noncovalent Cl···Cl Interactions. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 49(12), 807-811. https://doi.org/10.1134/S1070328423600213

Vancouver

Usol’tsev AN, Sonina AA, Korobeinikov NA, Adonin SA. Trimethylammonium Dichlorohexachlorotellurate(IV): Crystal Structure and Specific Features of Noncovalent Cl···Cl Interactions. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2023 Dec;49(12):807-811. doi: 10.1134/S1070328423600213

Author

Usol’tsev, A. N. ; Sonina, A. A. ; Korobeinikov, N. A. et al. / Trimethylammonium Dichlorohexachlorotellurate(IV): Crystal Structure and Specific Features of Noncovalent Cl···Cl Interactions. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2023 ; Vol. 49, No. 12. pp. 807-811.

BibTeX

@article{6f5ad5d0626544c4b1160100b6ea9407,
title = "Trimethylammonium Dichlorohexachlorotellurate(IV): Crystal Structure and Specific Features of Noncovalent Cl···Cl Interactions",
abstract = "The reaction of tellurium(IV) oxide with trimethylammonium chloride in the presence of gaseous chlorine in concentrated hydrochloric acid gives supramolecular dichlorohexachlorotellurate (Me3NH)2{[TeCl6](Cl2)} (I), whose structure is determined by X-ray diffraction (XRD) (CIF file CCDC no. 2217752). The data of elemental and XRD analyses suggest a restricted stability of the synthesized compound. Specific features of noncovalent Cl···Cl interactions in the crystal structure of compound I are studied by Raman spectroscopy.",
keywords = "XRD, halide complexes, halogen bond, noncovalent interactions, tellurium",
author = "Usol{\textquoteright}tsev, {A. N.} and Sonina, {A. A.} and Korobeinikov, {N. A.} and Adonin, {S. A.}",
note = "This work was supported by the Russian Science Foundation (project no. 18-73-10040) and the Ministry of Science and Higher Education of the Russian Federation (structural characterization of the samples, project no. 121031700313-8). The authors are grateful to the Center for Collective Use of the Nikolaev Institute of Inorganic Chemistry (Siberian Branch, Russian Academy of Sciences) for a possibility of obtaining the initial XRD data. Публикация для корректировки.",
year = "2023",
month = dec,
doi = "10.1134/S1070328423600213",
language = "English",
volume = "49",
pages = "807--811",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "12",

}

RIS

TY - JOUR

T1 - Trimethylammonium Dichlorohexachlorotellurate(IV): Crystal Structure and Specific Features of Noncovalent Cl···Cl Interactions

AU - Usol’tsev, A. N.

AU - Sonina, A. A.

AU - Korobeinikov, N. A.

AU - Adonin, S. A.

N1 - This work was supported by the Russian Science Foundation (project no. 18-73-10040) and the Ministry of Science and Higher Education of the Russian Federation (structural characterization of the samples, project no. 121031700313-8). The authors are grateful to the Center for Collective Use of the Nikolaev Institute of Inorganic Chemistry (Siberian Branch, Russian Academy of Sciences) for a possibility of obtaining the initial XRD data. Публикация для корректировки.

PY - 2023/12

Y1 - 2023/12

N2 - The reaction of tellurium(IV) oxide with trimethylammonium chloride in the presence of gaseous chlorine in concentrated hydrochloric acid gives supramolecular dichlorohexachlorotellurate (Me3NH)2{[TeCl6](Cl2)} (I), whose structure is determined by X-ray diffraction (XRD) (CIF file CCDC no. 2217752). The data of elemental and XRD analyses suggest a restricted stability of the synthesized compound. Specific features of noncovalent Cl···Cl interactions in the crystal structure of compound I are studied by Raman spectroscopy.

AB - The reaction of tellurium(IV) oxide with trimethylammonium chloride in the presence of gaseous chlorine in concentrated hydrochloric acid gives supramolecular dichlorohexachlorotellurate (Me3NH)2{[TeCl6](Cl2)} (I), whose structure is determined by X-ray diffraction (XRD) (CIF file CCDC no. 2217752). The data of elemental and XRD analyses suggest a restricted stability of the synthesized compound. Specific features of noncovalent Cl···Cl interactions in the crystal structure of compound I are studied by Raman spectroscopy.

KW - XRD

KW - halide complexes

KW - halogen bond

KW - noncovalent interactions

KW - tellurium

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85180124446&origin=inward&txGid=2eea75f2039ac7b8c0e697da37ca5aff

UR - https://www.mendeley.com/catalogue/c988117f-c211-35f9-9f88-54ee5f33fb79/

U2 - 10.1134/S1070328423600213

DO - 10.1134/S1070328423600213

M3 - Article

VL - 49

SP - 807

EP - 811

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 12

ER -

ID: 59546126