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Synthesis, crystal structure and fluorescent properties of indolo[3,2-b]carbazole-based metal–organic coordination polymers. / Khan, Il Son; Samsonenko, Denis G.; Irgashev, Roman A. и др.
в: Polyhedron, Том 141, 15.02.2018, стр. 337-342.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Synthesis, crystal structure and fluorescent properties of indolo[3,2-b]carbazole-based metal–organic coordination polymers
AU - Khan, Il Son
AU - Samsonenko, Denis G.
AU - Irgashev, Roman A.
AU - Kazin, Nikita A.
AU - Rusinov, Gennady L.
AU - Charushin, Valery N.
AU - Zavakhina, Marina S.
AU - Fedin, Vladimir P.
N1 - Publisher Copyright: © 2017 Elsevier Ltd
PY - 2018/2/15
Y1 - 2018/2/15
N2 - A new 5,11-dihydroindolo[3,2-b]carbazole-based bidentate ligand bearing two carboxylic groups, (3,3′-(indolo[3,2-b]carbazole-5,11-diyl)dipropionic acid, H2icdc), has been synthesized in two steps and then used for the construction of two metal–organic coordination polymers, namely [Zn3(dmf)2(icdc)3]·4DMF (1) and [Zn2(dabco)(icdc)2]·4NMP·4H2O (2) (dabco = 1,4-diazabicyclo[2.2.2]octane, DMF = N,N-dimethylformamide, NMP = N-methyl-2-pyrrolidone). Compound 1 has a layered structure, while compound 2 has a 3D framework structure. Both compounds display linker-based blue fluorescence.
AB - A new 5,11-dihydroindolo[3,2-b]carbazole-based bidentate ligand bearing two carboxylic groups, (3,3′-(indolo[3,2-b]carbazole-5,11-diyl)dipropionic acid, H2icdc), has been synthesized in two steps and then used for the construction of two metal–organic coordination polymers, namely [Zn3(dmf)2(icdc)3]·4DMF (1) and [Zn2(dabco)(icdc)2]·4NMP·4H2O (2) (dabco = 1,4-diazabicyclo[2.2.2]octane, DMF = N,N-dimethylformamide, NMP = N-methyl-2-pyrrolidone). Compound 1 has a layered structure, while compound 2 has a 3D framework structure. Both compounds display linker-based blue fluorescence.
KW - Coordination polymer
KW - Indolo[3,2-b]carbazoles
KW - Luminescence
KW - Metal–organic framework
KW - Zinc complexes
KW - Metal-organic framework
KW - MOFS
KW - DERIVATIVES
KW - FRAMEWORKS
UR - http://www.scopus.com/inward/record.url?scp=85040021673&partnerID=8YFLogxK
U2 - 10.1016/j.poly.2017.12.020
DO - 10.1016/j.poly.2017.12.020
M3 - Article
AN - SCOPUS:85040021673
VL - 141
SP - 337
EP - 342
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
ER -
ID: 9160187