Synthesis, crystal structure and fluorescent properties of indolo[3,2-b]carbazole-based metal–organic coordination polymers

Standard

Synthesis, crystal structure and fluorescent properties of indolo[3,2-b]carbazole-based metal–organic coordination polymers. / Khan, Il Son; Samsonenko, Denis G.; Irgashev, Roman A. et al.

In: Polyhedron, Vol. 141, 15.02.2018, p. 337-342.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{2d1a138f0f6f40008b24fddaa4d97300,

title = "Synthesis, crystal structure and fluorescent properties of indolo[3,2-b]carbazole-based metal–organic coordination polymers",

abstract = "A new 5,11-dihydroindolo[3,2-b]carbazole-based bidentate ligand bearing two carboxylic groups, (3,3′-(indolo[3,2-b]carbazole-5,11-diyl)dipropionic acid, H2icdc), has been synthesized in two steps and then used for the construction of two metal–organic coordination polymers, namely [Zn3(dmf)2(icdc)3]·4DMF (1) and [Zn2(dabco)(icdc)2]·4NMP·4H2O (2) (dabco = 1,4-diazabicyclo[2.2.2]octane, DMF = N,N-dimethylformamide, NMP = N-methyl-2-pyrrolidone). Compound 1 has a layered structure, while compound 2 has a 3D framework structure. Both compounds display linker-based blue fluorescence.",

keywords = "Coordination polymer, Indolo[3,2-b]carbazoles, Luminescence, Metal–organic framework, Zinc complexes, Metal-organic framework, MOFS, DERIVATIVES, FRAMEWORKS",

author = "Khan, {Il Son} and Samsonenko, {Denis G.} and Irgashev, {Roman A.} and Kazin, {Nikita A.} and Rusinov, {Gennady L.} and Charushin, {Valery N.} and Zavakhina, {Marina S.} and Fedin, {Vladimir P.}",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd",

year = "2018",

month = feb,

day = "15",

doi = "10.1016/j.poly.2017.12.020",

language = "English",

volume = "141",

pages = "337--342",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Synthesis, crystal structure and fluorescent properties of indolo[3,2-b]carbazole-based metal–organic coordination polymers

AU - Khan, Il Son

AU - Samsonenko, Denis G.

AU - Irgashev, Roman A.

AU - Kazin, Nikita A.

AU - Rusinov, Gennady L.

AU - Charushin, Valery N.

AU - Zavakhina, Marina S.

AU - Fedin, Vladimir P.

PY - 2018/2/15

Y1 - 2018/2/15

N2 - A new 5,11-dihydroindolo[3,2-b]carbazole-based bidentate ligand bearing two carboxylic groups, (3,3′-(indolo[3,2-b]carbazole-5,11-diyl)dipropionic acid, H2icdc), has been synthesized in two steps and then used for the construction of two metal–organic coordination polymers, namely [Zn3(dmf)2(icdc)3]·4DMF (1) and [Zn2(dabco)(icdc)2]·4NMP·4H2O (2) (dabco = 1,4-diazabicyclo[2.2.2]octane, DMF = N,N-dimethylformamide, NMP = N-methyl-2-pyrrolidone). Compound 1 has a layered structure, while compound 2 has a 3D framework structure. Both compounds display linker-based blue fluorescence.

AB - A new 5,11-dihydroindolo[3,2-b]carbazole-based bidentate ligand bearing two carboxylic groups, (3,3′-(indolo[3,2-b]carbazole-5,11-diyl)dipropionic acid, H2icdc), has been synthesized in two steps and then used for the construction of two metal–organic coordination polymers, namely [Zn3(dmf)2(icdc)3]·4DMF (1) and [Zn2(dabco)(icdc)2]·4NMP·4H2O (2) (dabco = 1,4-diazabicyclo[2.2.2]octane, DMF = N,N-dimethylformamide, NMP = N-methyl-2-pyrrolidone). Compound 1 has a layered structure, while compound 2 has a 3D framework structure. Both compounds display linker-based blue fluorescence.

KW - Coordination polymer

KW - Indolo[3,2-b]carbazoles

KW - Luminescence

KW - Metal–organic framework

KW - Zinc complexes

KW - Metal-organic framework

KW - MOFS

KW - DERIVATIVES

KW - FRAMEWORKS

UR - http://www.scopus.com/inward/record.url?scp=85040021673&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2017.12.020

DO - 10.1016/j.poly.2017.12.020

M3 - Article

AN - SCOPUS:85040021673

VL - 141

SP - 337

EP - 342

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

ID: 9160187