Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Synthesis and growth of new rare earth borates KCaR(BO3)2 (R= La, Pr and Nd). / Kuznetsov, A. B.; Kokh, K. A.; Kononova, N. G. и др.
в: Journal of Solid State Chemistry, Том 282, 121091, 02.2020.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Synthesis and growth of new rare earth borates KCaR(BO3)2 (R= La, Pr and Nd)
AU - Kuznetsov, A. B.
AU - Kokh, K. A.
AU - Kononova, N. G.
AU - Shevchenko, V. S.
AU - Kaneva, V.
AU - Uralbekov, B.
AU - Svetlichnyi, V. A.
AU - Kokh, A. E.
PY - 2020/2
Y1 - 2020/2
N2 - Novel KCaR(BO3)2 (R = La, Pr and Nd) compounds have been obtained by solid-state synthesis. Specifically, single crystals of KCaNd(BO3)2 and KCaPr(BO3)2 were grown by using a top seeded solution growth method from the KBO2 flux. These crystal compounds belong to the orthorhombic system, Pbca space group. KCaLa(BO3)2 exhibits high transparency in the range of 200–900 nm. Pr and Nd compounds have a strong emission bands that are related to the well-known electron transition of Pr3+ (3P0 → 3H6 at 630 nm, 3P0 → 3F2 at 670 nm) and Nd3+ (4F3/2 → 4I9/2 at 875 nm, 4F3/2 → 4I11/2 at 1054 nm).
AB - Novel KCaR(BO3)2 (R = La, Pr and Nd) compounds have been obtained by solid-state synthesis. Specifically, single crystals of KCaNd(BO3)2 and KCaPr(BO3)2 were grown by using a top seeded solution growth method from the KBO2 flux. These crystal compounds belong to the orthorhombic system, Pbca space group. KCaLa(BO3)2 exhibits high transparency in the range of 200–900 nm. Pr and Nd compounds have a strong emission bands that are related to the well-known electron transition of Pr3+ (3P0 → 3H6 at 630 nm, 3P0 → 3F2 at 670 nm) and Nd3+ (4F3/2 → 4I9/2 at 875 nm, 4F3/2 → 4I11/2 at 1054 nm).
KW - Borates
KW - Crystal growth
KW - Luminescence
KW - Rare earth
KW - Solin-state synthesis
KW - CRYSTAL-STRUCTURE
KW - OPTICAL-PROPERTIES
KW - YB
KW - NLO CRYSTALS
UR - http://www.scopus.com/inward/record.url?scp=85080967372&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2019.121091
DO - 10.1016/j.jssc.2019.121091
M3 - Article
AN - SCOPUS:85080967372
VL - 282
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
M1 - 121091
ER -
ID: 23948589