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Synthesis and growth of new rare earth borates KCaR(BO3)2 (R= La, Pr and Nd). / Kuznetsov, A. B.; Kokh, K. A.; Kononova, N. G. et al.

In: Journal of Solid State Chemistry, Vol. 282, 121091, 02.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Kuznetsov, AB, Kokh, KA, Kononova, NG, Shevchenko, VS, Kaneva, V, Uralbekov, B, Svetlichnyi, VA & Kokh, AE 2020, 'Synthesis and growth of new rare earth borates KCaR(BO3)2 (R= La, Pr and Nd)', Journal of Solid State Chemistry, vol. 282, 121091. https://doi.org/10.1016/j.jssc.2019.121091

APA

Kuznetsov, A. B., Kokh, K. A., Kononova, N. G., Shevchenko, V. S., Kaneva, V., Uralbekov, B., Svetlichnyi, V. A., & Kokh, A. E. (2020). Synthesis and growth of new rare earth borates KCaR(BO3)2 (R= La, Pr and Nd). Journal of Solid State Chemistry, 282, [121091]. https://doi.org/10.1016/j.jssc.2019.121091

Vancouver

Kuznetsov AB, Kokh KA, Kononova NG, Shevchenko VS, Kaneva V, Uralbekov B et al. Synthesis and growth of new rare earth borates KCaR(BO3)2 (R= La, Pr and Nd). Journal of Solid State Chemistry. 2020 Feb;282:121091. doi: 10.1016/j.jssc.2019.121091

Author

Kuznetsov, A. B. ; Kokh, K. A. ; Kononova, N. G. et al. / Synthesis and growth of new rare earth borates KCaR(BO3)2 (R= La, Pr and Nd). In: Journal of Solid State Chemistry. 2020 ; Vol. 282.

BibTeX

@article{b1f1cd639d95443d8a0112f2b4211be8,
title = "Synthesis and growth of new rare earth borates KCaR(BO3)2 (R= La, Pr and Nd)",
abstract = "Novel KCaR(BO3)2 (R ​= ​La, Pr and Nd) compounds have been obtained by solid-state synthesis. Specifically, single crystals of KCaNd(BO3)2 and KCaPr(BO3)2 were grown by using a top seeded solution growth method from the KBO2 flux. These crystal compounds belong to the orthorhombic system, Pbca space group. KCaLa(BO3)2 exhibits high transparency in the range of 200–900 ​nm. Pr and Nd compounds have a strong emission bands that are related to the well-known electron transition of Pr3+ (3P0 → 3H6 at 630 ​nm, 3P0 → 3F2 at 670 ​nm) and Nd3+ (4F3/2 ​→ ​4I9/2 ​at 875 ​nm, 4F3/2 ​→ ​4I11/2 ​at 1054 ​nm).",
keywords = "Borates, Crystal growth, Luminescence, Rare earth, Solin-state synthesis, CRYSTAL-STRUCTURE, OPTICAL-PROPERTIES, YB, NLO CRYSTALS",
author = "Kuznetsov, {A. B.} and Kokh, {K. A.} and Kononova, {N. G.} and Shevchenko, {V. S.} and V. Kaneva and B. Uralbekov and Svetlichnyi, {V. A.} and Kokh, {A. E.}",
year = "2020",
month = feb,
doi = "10.1016/j.jssc.2019.121091",
language = "English",
volume = "282",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "Academic Press Inc.",

}

RIS

TY - JOUR

T1 - Synthesis and growth of new rare earth borates KCaR(BO3)2 (R= La, Pr and Nd)

AU - Kuznetsov, A. B.

AU - Kokh, K. A.

AU - Kononova, N. G.

AU - Shevchenko, V. S.

AU - Kaneva, V.

AU - Uralbekov, B.

AU - Svetlichnyi, V. A.

AU - Kokh, A. E.

PY - 2020/2

Y1 - 2020/2

N2 - Novel KCaR(BO3)2 (R ​= ​La, Pr and Nd) compounds have been obtained by solid-state synthesis. Specifically, single crystals of KCaNd(BO3)2 and KCaPr(BO3)2 were grown by using a top seeded solution growth method from the KBO2 flux. These crystal compounds belong to the orthorhombic system, Pbca space group. KCaLa(BO3)2 exhibits high transparency in the range of 200–900 ​nm. Pr and Nd compounds have a strong emission bands that are related to the well-known electron transition of Pr3+ (3P0 → 3H6 at 630 ​nm, 3P0 → 3F2 at 670 ​nm) and Nd3+ (4F3/2 ​→ ​4I9/2 ​at 875 ​nm, 4F3/2 ​→ ​4I11/2 ​at 1054 ​nm).

AB - Novel KCaR(BO3)2 (R ​= ​La, Pr and Nd) compounds have been obtained by solid-state synthesis. Specifically, single crystals of KCaNd(BO3)2 and KCaPr(BO3)2 were grown by using a top seeded solution growth method from the KBO2 flux. These crystal compounds belong to the orthorhombic system, Pbca space group. KCaLa(BO3)2 exhibits high transparency in the range of 200–900 ​nm. Pr and Nd compounds have a strong emission bands that are related to the well-known electron transition of Pr3+ (3P0 → 3H6 at 630 ​nm, 3P0 → 3F2 at 670 ​nm) and Nd3+ (4F3/2 ​→ ​4I9/2 ​at 875 ​nm, 4F3/2 ​→ ​4I11/2 ​at 1054 ​nm).

KW - Borates

KW - Crystal growth

KW - Luminescence

KW - Rare earth

KW - Solin-state synthesis

KW - CRYSTAL-STRUCTURE

KW - OPTICAL-PROPERTIES

KW - YB

KW - NLO CRYSTALS

UR - http://www.scopus.com/inward/record.url?scp=85080967372&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2019.121091

DO - 10.1016/j.jssc.2019.121091

M3 - Article

AN - SCOPUS:85080967372

VL - 282

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

M1 - 121091

ER -

ID: 23948589