Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review. / Levitsky, Mikhail M.; Zubavichus, Yan V.; Korlyukov, Alexander A. и др.
в: Journal of Cluster Science, Том 30, № 5, 01.09.2019, стр. 1283-1316.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review
AU - Levitsky, Mikhail M.
AU - Zubavichus, Yan V.
AU - Korlyukov, Alexander A.
AU - Khrustalev, Victor N.
AU - Shubina, Elena S.
AU - Bilyachenko, Alexey N.
N1 - Publisher Copyright: © 2019, Springer Science+Business Media, LLC, part of Springer Nature.
PY - 2019/9/1
Y1 - 2019/9/1
N2 - In the present paper, a rapidly developing field of polynuclear cage metallasilsesquioxanes and metallagermsesquioxanes chemistry is surveyed. Deliberate synthesis techniques aimed at the cages of specific nuclearity are described with the emphasis placed onto analysis of similarities and differences between silicon- and germanium-based substances. General approaches towards design of polymeric supramolecular assemblies based on cage metallasilsesquioxanes and metallagermsesquioxanes are outlined and illustrated with appropriate examples. Striking catalytic properties of the title compounds in homogeneous oxidation reactions are noted as one of their prospective application field.
AB - In the present paper, a rapidly developing field of polynuclear cage metallasilsesquioxanes and metallagermsesquioxanes chemistry is surveyed. Deliberate synthesis techniques aimed at the cages of specific nuclearity are described with the emphasis placed onto analysis of similarities and differences between silicon- and germanium-based substances. General approaches towards design of polymeric supramolecular assemblies based on cage metallasilsesquioxanes and metallagermsesquioxanes are outlined and illustrated with appropriate examples. Striking catalytic properties of the title compounds in homogeneous oxidation reactions are noted as one of their prospective application field.
KW - Cage compounds
KW - Catalytic activity
KW - Coordination polymers
KW - High-nuclearity
KW - Metallagermsesquioxanes
KW - Metallasilsesquioxanes
KW - Single-crystal X-ray diffraction
KW - Supramolecular design
UR - http://www.scopus.com/inward/record.url?scp=85065395332&partnerID=8YFLogxK
U2 - 10.1007/s10876-019-01567-y
DO - 10.1007/s10876-019-01567-y
M3 - Article
AN - SCOPUS:85065395332
VL - 30
SP - 1283
EP - 1316
JO - Journal of Cluster Science
JF - Journal of Cluster Science
SN - 1040-7278
IS - 5
ER -
ID: 25465131