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Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review. / Levitsky, Mikhail M.; Zubavichus, Yan V.; Korlyukov, Alexander A. et al.

In: Journal of Cluster Science, Vol. 30, No. 5, 01.09.2019, p. 1283-1316.

Research output: Contribution to journal › Article › peer-review

Harvard

Levitsky, MM, Zubavichus, YV, Korlyukov, AA, Khrustalev, VN, Shubina, ES & Bilyachenko, AN 2019, 'Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review', Journal of Cluster Science, vol. 30, no. 5, pp. 1283-1316. https://doi.org/10.1007/s10876-019-01567-y

APA

Levitsky, M. M., Zubavichus, Y. V., Korlyukov, A. A., Khrustalev, V. N., Shubina, E. S., & Bilyachenko, A. N. (2019). Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review. Journal of Cluster Science, 30(5), 1283-1316. https://doi.org/10.1007/s10876-019-01567-y

Vancouver

Levitsky MM, Zubavichus YV, Korlyukov AA, Khrustalev VN, Shubina ES, Bilyachenko AN. Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review. Journal of Cluster Science. 2019 Sept 1;30(5):1283-1316. doi: 10.1007/s10876-019-01567-y

Author

Levitsky, Mikhail M. ; Zubavichus, Yan V. ; Korlyukov, Alexander A. et al. / Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review. In: Journal of Cluster Science. 2019 ; Vol. 30, No. 5. pp. 1283-1316.

BibTeX

@article{0b4d6c90f8ab4f8ea5cedec4e6403e5e,
title = "Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review",
abstract = "In the present paper, a rapidly developing field of polynuclear cage metallasilsesquioxanes and metallagermsesquioxanes chemistry is surveyed. Deliberate synthesis techniques aimed at the cages of specific nuclearity are described with the emphasis placed onto analysis of similarities and differences between silicon- and germanium-based substances. General approaches towards design of polymeric supramolecular assemblies based on cage metallasilsesquioxanes and metallagermsesquioxanes are outlined and illustrated with appropriate examples. Striking catalytic properties of the title compounds in homogeneous oxidation reactions are noted as one of their prospective application field.",
keywords = "Cage compounds, Catalytic activity, Coordination polymers, High-nuclearity, Metallagermsesquioxanes, Metallasilsesquioxanes, Single-crystal X-ray diffraction, Supramolecular design",
author = "Levitsky, {Mikhail M.} and Zubavichus, {Yan V.} and Korlyukov, {Alexander A.} and Khrustalev, {Victor N.} and Shubina, {Elena S.} and Bilyachenko, {Alexey N.}",
note = "Publisher Copyright: {\textcopyright} 2019, Springer Science+Business Media, LLC, part of Springer Nature.",
year = "2019",
month = sep,
day = "1",
doi = "10.1007/s10876-019-01567-y",
language = "English",
volume = "30",
pages = "1283--1316",
journal = "Journal of Cluster Science",
issn = "1040-7278",
publisher = "Springer New York",
number = "5",

}

RIS

TY - JOUR

T1 - Silicon and Germanium-Based Sesquioxanes as Versatile Building Blocks for Cage Metallacomplexes. A Review

AU - Levitsky, Mikhail M.

AU - Zubavichus, Yan V.

AU - Korlyukov, Alexander A.

AU - Khrustalev, Victor N.

AU - Shubina, Elena S.

AU - Bilyachenko, Alexey N.

N1 - Publisher Copyright: © 2019, Springer Science+Business Media, LLC, part of Springer Nature.

PY - 2019/9/1

Y1 - 2019/9/1

N2 - In the present paper, a rapidly developing field of polynuclear cage metallasilsesquioxanes and metallagermsesquioxanes chemistry is surveyed. Deliberate synthesis techniques aimed at the cages of specific nuclearity are described with the emphasis placed onto analysis of similarities and differences between silicon- and germanium-based substances. General approaches towards design of polymeric supramolecular assemblies based on cage metallasilsesquioxanes and metallagermsesquioxanes are outlined and illustrated with appropriate examples. Striking catalytic properties of the title compounds in homogeneous oxidation reactions are noted as one of their prospective application field.

AB - In the present paper, a rapidly developing field of polynuclear cage metallasilsesquioxanes and metallagermsesquioxanes chemistry is surveyed. Deliberate synthesis techniques aimed at the cages of specific nuclearity are described with the emphasis placed onto analysis of similarities and differences between silicon- and germanium-based substances. General approaches towards design of polymeric supramolecular assemblies based on cage metallasilsesquioxanes and metallagermsesquioxanes are outlined and illustrated with appropriate examples. Striking catalytic properties of the title compounds in homogeneous oxidation reactions are noted as one of their prospective application field.

KW - Cage compounds

KW - Catalytic activity

KW - Coordination polymers

KW - High-nuclearity

KW - Metallagermsesquioxanes

KW - Metallasilsesquioxanes

KW - Single-crystal X-ray diffraction

KW - Supramolecular design

UR - http://www.scopus.com/inward/record.url?scp=85065395332&partnerID=8YFLogxK

U2 - 10.1007/s10876-019-01567-y

DO - 10.1007/s10876-019-01567-y

M3 - Article

AN - SCOPUS:85065395332

VL - 30

SP - 1283

EP - 1316

JO - Journal of Cluster Science

JF - Journal of Cluster Science

SN - 1040-7278

IS - 5

ER -

ID: 25465131