Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Screw-like morphology of silicoaluminophosphate-11 (SAPO-11) crystallized in ethanol medium. / Tiuliukova, I. A.; Rudina, N. A.; Lysikov, A. I. и др.
в: Materials Letters, Том 228, 01.10.2018, стр. 61-64.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Screw-like morphology of silicoaluminophosphate-11 (SAPO-11) crystallized in ethanol medium
AU - Tiuliukova, I. A.
AU - Rudina, N. A.
AU - Lysikov, A. I.
AU - Cherepanova, S. V.
AU - Parkhomchuk, E. V.
N1 - Publisher Copyright: © 2018 Elsevier B.V.
PY - 2018/10/1
Y1 - 2018/10/1
N2 - Silicoaluminophosphate-11 (SAPO-11) crystals were synthesized in different media – water and ethanol – by the two-stage hydrothermal method using ultrasonic pretreatment of precursor mixture. Changing of the synthesis medium from water to ethanol leads to transformation of SAPO-11 morphology: from pseudo-spherical aggregative crystals to novel screw-like morphology. SAPO-11 crystals, synthesized in ethanol medium (Et-SAPO-11), have remarkable textural properties: the greater values of BET surface area and micropore/mesopores volume, compared with crystals, obtained in the water medium (W-SAPO-11). Besides, the acidity of Et-SAPO-11 is lower than that of W-SAPO-11 due to hindered incorporation of silicon into aluminophosphate lattice in ethanol medium.
AB - Silicoaluminophosphate-11 (SAPO-11) crystals were synthesized in different media – water and ethanol – by the two-stage hydrothermal method using ultrasonic pretreatment of precursor mixture. Changing of the synthesis medium from water to ethanol leads to transformation of SAPO-11 morphology: from pseudo-spherical aggregative crystals to novel screw-like morphology. SAPO-11 crystals, synthesized in ethanol medium (Et-SAPO-11), have remarkable textural properties: the greater values of BET surface area and micropore/mesopores volume, compared with crystals, obtained in the water medium (W-SAPO-11). Besides, the acidity of Et-SAPO-11 is lower than that of W-SAPO-11 due to hindered incorporation of silicon into aluminophosphate lattice in ethanol medium.
KW - Crystal morphology
KW - Ethanol medium
KW - Porous materials
KW - SAPO-11
KW - Silicoaluminophosphate
KW - Texture
KW - SILICON
KW - HYDROISOMERIZATION
KW - MOLECULAR-SIEVES
KW - NONAQUEOUS MEDIA
KW - PT/SAPO-11
KW - ALKENES
KW - CATALYTIC-PROPERTIES
KW - IMPROVEMENT
UR - http://www.scopus.com/inward/record.url?scp=85048465497&partnerID=8YFLogxK
U2 - 10.1016/j.matlet.2018.05.118
DO - 10.1016/j.matlet.2018.05.118
M3 - Article
AN - SCOPUS:85048465497
VL - 228
SP - 61
EP - 64
JO - Materials Letters
JF - Materials Letters
SN - 0167-577X
ER -
ID: 14048024