Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Reactions of Triangular Molybdenum and Tungsten Clusters with Tetrabromocatechol. / Petrov, P. A.; Filippova, E. A.; Giniyatullin, V. R. и др.
в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 49, № 8, 2023, стр. 465-470.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Reactions of Triangular Molybdenum and Tungsten Clusters with Tetrabromocatechol
AU - Petrov, P. A.
AU - Filippova, E. A.
AU - Giniyatullin, V. R.
AU - Sukhikh, T. S.
AU - Sheven’, D. G.
AU - Gushchin, A. L.
AU - Sokolov, M. N.
N1 - This study was supported by the Ministry of Science and Higher Education of the Russian Federation (project nos. 121031700313-8 and 121031700315-2). Публикация для корректировки.
PY - 2023
Y1 - 2023
N2 - The reaction of cluster complex (nBu4N)2[Mo3Se7Br6] with tetrabromocatechol (H2Tbc) in the presence of Et3N and Ph4PBr results in the formation of (Ph4P)2[Mo3Se7(Tbc)3]∙2MeOH (Ia∙2MeOH). Under the same conditions, the tungsten analogue (nBu4N)2[W3S7Br6] is completely or partly destroyed to give the complex (Ph4P)(Et3NH)[WO2(Tbc)2] (II). The structures of Ia·2MeOH and II were established by X-ray diffraction analysis (CCDC nos. 2213900 and 2213901, respectively). The redox properties of complex Ia and related (Ph4P)2[Mo3S7(Tbc)3] (Ib) and (Ph4P)2[Mo3S7(Tcc)3] (Ic) (Tcc is tetrachlorocatecholate) were also studied by cyclic voltammetry.
AB - The reaction of cluster complex (nBu4N)2[Mo3Se7Br6] with tetrabromocatechol (H2Tbc) in the presence of Et3N and Ph4PBr results in the formation of (Ph4P)2[Mo3Se7(Tbc)3]∙2MeOH (Ia∙2MeOH). Under the same conditions, the tungsten analogue (nBu4N)2[W3S7Br6] is completely or partly destroyed to give the complex (Ph4P)(Et3NH)[WO2(Tbc)2] (II). The structures of Ia·2MeOH and II were established by X-ray diffraction analysis (CCDC nos. 2213900 and 2213901, respectively). The redox properties of complex Ia and related (Ph4P)2[Mo3S7(Tbc)3] (Ib) and (Ph4P)2[Mo3S7(Tcc)3] (Ic) (Tcc is tetrachlorocatecholate) were also studied by cyclic voltammetry.
KW - clusters
KW - cyclic voltammetry
KW - molybdenum
KW - redox-active ligands
KW - tungsten
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85168687881&origin=inward&txGid=102f16216de5af0ce527cf2477b6f9b3
UR - https://www.mendeley.com/catalogue/e112525b-fd1f-35d3-b458-f44f9d35ee88/
U2 - 10.1134/S1070328423600390
DO - 10.1134/S1070328423600390
M3 - Article
VL - 49
SP - 465
EP - 470
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 8
ER -
ID: 59557676