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Reactions of Triangular Molybdenum and Tungsten Clusters with Tetrabromocatechol. / Petrov, P. A.; Filippova, E. A.; Giniyatullin, V. R. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 49, No. 8, 2023, p. 465-470.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA, Filippova, EA, Giniyatullin, VR, Sukhikh, TS, Sheven’, DG, Gushchin, AL & Sokolov, MN 2023, 'Reactions of Triangular Molybdenum and Tungsten Clusters with Tetrabromocatechol', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 49, no. 8, pp. 465-470. https://doi.org/10.1134/S1070328423600390

APA

Petrov, P. A., Filippova, E. A., Giniyatullin, V. R., Sukhikh, T. S., Sheven’, D. G., Gushchin, A. L., & Sokolov, M. N. (2023). Reactions of Triangular Molybdenum and Tungsten Clusters with Tetrabromocatechol. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 49(8), 465-470. https://doi.org/10.1134/S1070328423600390

Vancouver

Petrov PA, Filippova EA, Giniyatullin VR, Sukhikh TS, Sheven’ DG, Gushchin AL et al. Reactions of Triangular Molybdenum and Tungsten Clusters with Tetrabromocatechol. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2023;49(8):465-470. doi: 10.1134/S1070328423600390

Author

Petrov, P. A. ; Filippova, E. A. ; Giniyatullin, V. R. et al. / Reactions of Triangular Molybdenum and Tungsten Clusters with Tetrabromocatechol. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2023 ; Vol. 49, No. 8. pp. 465-470.

BibTeX

@article{91c098c0ac624126a4ae174f646600a1,
title = "Reactions of Triangular Molybdenum and Tungsten Clusters with Tetrabromocatechol",
abstract = "The reaction of cluster complex (nBu4N)2[Mo3Se7Br6] with tetrabromocatechol (H2Tbc) in the presence of Et3N and Ph4PBr results in the formation of (Ph4P)2[Mo3Se7(Tbc)3]∙2MeOH (Ia∙2MeOH). Under the same conditions, the tungsten analogue (nBu4N)2[W3S7Br6] is completely or partly destroyed to give the complex (Ph4P)(Et3NH)[WO2(Tbc)2] (II). The structures of Ia·2MeOH and II were established by X-ray diffraction analysis (CCDC nos. 2213900 and 2213901, respectively). The redox properties of complex Ia and related (Ph4P)2[Mo3S7(Tbc)3] (Ib) and (Ph4P)2[Mo3S7(Tcc)3] (Ic) (Tcc is tetrachlorocatecholate) were also studied by cyclic voltammetry.",
keywords = "clusters, cyclic voltammetry, molybdenum, redox-active ligands, tungsten",
author = "Petrov, {P. A.} and Filippova, {E. A.} and Giniyatullin, {V. R.} and Sukhikh, {T. S.} and Sheven{\textquoteright}, {D. G.} and Gushchin, {A. L.} and Sokolov, {M. N.}",
note = "This study was supported by the Ministry of Science and Higher Education of the Russian Federation (project nos. 121031700313-8 and 121031700315-2). Публикация для корректировки.",
year = "2023",
doi = "10.1134/S1070328423600390",
language = "English",
volume = "49",
pages = "465--470",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "8",

}

RIS

TY - JOUR

T1 - Reactions of Triangular Molybdenum and Tungsten Clusters with Tetrabromocatechol

AU - Petrov, P. A.

AU - Filippova, E. A.

AU - Giniyatullin, V. R.

AU - Sukhikh, T. S.

AU - Sheven’, D. G.

AU - Gushchin, A. L.

AU - Sokolov, M. N.

N1 - This study was supported by the Ministry of Science and Higher Education of the Russian Federation (project nos. 121031700313-8 and 121031700315-2). Публикация для корректировки.

PY - 2023

Y1 - 2023

N2 - The reaction of cluster complex (nBu4N)2[Mo3Se7Br6] with tetrabromocatechol (H2Tbc) in the presence of Et3N and Ph4PBr results in the formation of (Ph4P)2[Mo3Se7(Tbc)3]∙2MeOH (Ia∙2MeOH). Under the same conditions, the tungsten analogue (nBu4N)2[W3S7Br6] is completely or partly destroyed to give the complex (Ph4P)(Et3NH)[WO2(Tbc)2] (II). The structures of Ia·2MeOH and II were established by X-ray diffraction analysis (CCDC nos. 2213900 and 2213901, respectively). The redox properties of complex Ia and related (Ph4P)2[Mo3S7(Tbc)3] (Ib) and (Ph4P)2[Mo3S7(Tcc)3] (Ic) (Tcc is tetrachlorocatecholate) were also studied by cyclic voltammetry.

AB - The reaction of cluster complex (nBu4N)2[Mo3Se7Br6] with tetrabromocatechol (H2Tbc) in the presence of Et3N and Ph4PBr results in the formation of (Ph4P)2[Mo3Se7(Tbc)3]∙2MeOH (Ia∙2MeOH). Under the same conditions, the tungsten analogue (nBu4N)2[W3S7Br6] is completely or partly destroyed to give the complex (Ph4P)(Et3NH)[WO2(Tbc)2] (II). The structures of Ia·2MeOH and II were established by X-ray diffraction analysis (CCDC nos. 2213900 and 2213901, respectively). The redox properties of complex Ia and related (Ph4P)2[Mo3S7(Tbc)3] (Ib) and (Ph4P)2[Mo3S7(Tcc)3] (Ic) (Tcc is tetrachlorocatecholate) were also studied by cyclic voltammetry.

KW - clusters

KW - cyclic voltammetry

KW - molybdenum

KW - redox-active ligands

KW - tungsten

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85168687881&origin=inward&txGid=102f16216de5af0ce527cf2477b6f9b3

UR - https://www.mendeley.com/catalogue/e112525b-fd1f-35d3-b458-f44f9d35ee88/

U2 - 10.1134/S1070328423600390

DO - 10.1134/S1070328423600390

M3 - Article

VL - 49

SP - 465

EP - 470

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 8

ER -

ID: 59557676