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Production of hydrogen-rich gas by formic acid decomposition over CuO-CeO2/γ-Al2O3 catalyst. / Pechenkin, Alexey; Badmaev, Sukhe; Belyaev, Vladimir и др.
в: Energies, Том 12, № 18, 3577, 19.09.2019.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Production of hydrogen-rich gas by formic acid decomposition over CuO-CeO2/γ-Al2O3 catalyst
AU - Pechenkin, Alexey
AU - Badmaev, Sukhe
AU - Belyaev, Vladimir
AU - Sobyanin, Vladimir
PY - 2019/9/19
Y1 - 2019/9/19
N2 - Formic acid decomposition to H2-rich gas was investigated over a CuO-CeO2/γ-Al2O3 catalyst. The catalyst was characterized by XRD, HR TEM and EDX methods. A 100% conversion of formic acid was observed over the copper-ceria catalyst under ambient pressure, at 200–300 ◦C, N2:HCOOH = 75:25 vol.% and flow rate 3500–35,000 h−1 with H2 yield of 98%, wherein outlet CO concentration is below the equilibrium data (<0.5 vol.%). The copper-ceria catalyst proved to be promising for multifuel processor application, and the H2 generation from dimethoxymethane, methanol, dimethyl ether and formic acid on the same catalyst for fuel cell supply.
AB - Formic acid decomposition to H2-rich gas was investigated over a CuO-CeO2/γ-Al2O3 catalyst. The catalyst was characterized by XRD, HR TEM and EDX methods. A 100% conversion of formic acid was observed over the copper-ceria catalyst under ambient pressure, at 200–300 ◦C, N2:HCOOH = 75:25 vol.% and flow rate 3500–35,000 h−1 with H2 yield of 98%, wherein outlet CO concentration is below the equilibrium data (<0.5 vol.%). The copper-ceria catalyst proved to be promising for multifuel processor application, and the H2 generation from dimethoxymethane, methanol, dimethyl ether and formic acid on the same catalyst for fuel cell supply.
KW - Copper catalyst
KW - CuO-CeO/γ-AlO
KW - Formic acid decomposition
KW - Fuel cell
KW - Hydrogen production
KW - Multifuel processor
KW - Oxygenates
KW - OXIDATION
KW - DIMETHOXYMETHANE
KW - formic acid decomposition
KW - COPPER
KW - CO
KW - hydrogen production
KW - CuO-CeO2/gamma-Al2O3
KW - oxygenates
KW - CUO/CEO2
KW - fuel cell
KW - PD
KW - multifuel processor
KW - copper catalyst
KW - CuO-CeO2/γ-Al2O3
UR - http://www.scopus.com/inward/record.url?scp=85072542374&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/ae24d536-20ae-38bf-9e24-94430b7b25c5/
U2 - 10.3390/en12183577
DO - 10.3390/en12183577
M3 - Article
AN - SCOPUS:85072542374
VL - 12
JO - Energies
JF - Energies
SN - 1996-1073
IS - 18
M1 - 3577
ER -
ID: 21610116