Standard

Production of hydrogen-rich gas by formic acid decomposition over CuO-CeO2/γ-Al2O3 catalyst. / Pechenkin, Alexey; Badmaev, Sukhe; Belyaev, Vladimir et al.

In: Energies, Vol. 12, No. 18, 3577, 19.09.2019.

Research output: Contribution to journal › Article › peer-review

Harvard

Pechenkin, A, Badmaev, S, Belyaev, V & Sobyanin, V 2019, 'Production of hydrogen-rich gas by formic acid decomposition over CuO-CeO2/γ-Al2O3 catalyst', Energies, vol. 12, no. 18, 3577. https://doi.org/10.3390/en12183577

APA

Pechenkin, A., Badmaev, S., Belyaev, V., & Sobyanin, V. (2019). Production of hydrogen-rich gas by formic acid decomposition over CuO-CeO2/γ-Al2O3 catalyst. Energies, 12(18), [3577]. https://doi.org/10.3390/en12183577

Vancouver

Pechenkin A, Badmaev S, Belyaev V, Sobyanin V. Production of hydrogen-rich gas by formic acid decomposition over CuO-CeO2/γ-Al2O3 catalyst. Energies. 2019 Sept 19;12(18):3577. doi: 10.3390/en12183577

Author

Pechenkin, Alexey ; Badmaev, Sukhe ; Belyaev, Vladimir et al. / Production of hydrogen-rich gas by formic acid decomposition over CuO-CeO2/γ-Al2O3 catalyst. In: Energies. 2019 ; Vol. 12, No. 18.

BibTeX

@article{8c7a1ad8ab8c430b91b1bf8338c79250,
title = "Production of hydrogen-rich gas by formic acid decomposition over CuO-CeO2/γ-Al2O3 catalyst",
abstract = "Formic acid decomposition to H2-rich gas was investigated over a CuO-CeO2/γ-Al2O3 catalyst. The catalyst was characterized by XRD, HR TEM and EDX methods. A 100% conversion of formic acid was observed over the copper-ceria catalyst under ambient pressure, at 200–300 ◦C, N2:HCOOH = 75:25 vol.% and flow rate 3500–35,000 h−1 with H2 yield of 98%, wherein outlet CO concentration is below the equilibrium data (<0.5 vol.%). The copper-ceria catalyst proved to be promising for multifuel processor application, and the H2 generation from dimethoxymethane, methanol, dimethyl ether and formic acid on the same catalyst for fuel cell supply.",
keywords = "Copper catalyst, CuO-CeO/γ-AlO, Formic acid decomposition, Fuel cell, Hydrogen production, Multifuel processor, Oxygenates, OXIDATION, DIMETHOXYMETHANE, formic acid decomposition, COPPER, CO, hydrogen production, CuO-CeO2/gamma-Al2O3, oxygenates, CUO/CEO2, fuel cell, PD, multifuel processor, copper catalyst, CuO-CeO2/γ-Al2O3",
author = "Alexey Pechenkin and Sukhe Badmaev and Vladimir Belyaev and Vladimir Sobyanin",
year = "2019",
month = sep,
day = "19",
doi = "10.3390/en12183577",
language = "English",
volume = "12",
journal = "Energies",
issn = "1996-1073",
publisher = "MDPI AG",
number = "18",

}

RIS

TY - JOUR

T1 - Production of hydrogen-rich gas by formic acid decomposition over CuO-CeO2/γ-Al2O3 catalyst

AU - Pechenkin, Alexey

AU - Badmaev, Sukhe

AU - Belyaev, Vladimir

AU - Sobyanin, Vladimir

PY - 2019/9/19

Y1 - 2019/9/19

N2 - Formic acid decomposition to H2-rich gas was investigated over a CuO-CeO2/γ-Al2O3 catalyst. The catalyst was characterized by XRD, HR TEM and EDX methods. A 100% conversion of formic acid was observed over the copper-ceria catalyst under ambient pressure, at 200–300 ◦C, N2:HCOOH = 75:25 vol.% and flow rate 3500–35,000 h−1 with H2 yield of 98%, wherein outlet CO concentration is below the equilibrium data (<0.5 vol.%). The copper-ceria catalyst proved to be promising for multifuel processor application, and the H2 generation from dimethoxymethane, methanol, dimethyl ether and formic acid on the same catalyst for fuel cell supply.

AB - Formic acid decomposition to H2-rich gas was investigated over a CuO-CeO2/γ-Al2O3 catalyst. The catalyst was characterized by XRD, HR TEM and EDX methods. A 100% conversion of formic acid was observed over the copper-ceria catalyst under ambient pressure, at 200–300 ◦C, N2:HCOOH = 75:25 vol.% and flow rate 3500–35,000 h−1 with H2 yield of 98%, wherein outlet CO concentration is below the equilibrium data (<0.5 vol.%). The copper-ceria catalyst proved to be promising for multifuel processor application, and the H2 generation from dimethoxymethane, methanol, dimethyl ether and formic acid on the same catalyst for fuel cell supply.

KW - Copper catalyst

KW - CuO-CeO/γ-AlO

KW - Formic acid decomposition

KW - Fuel cell

KW - Hydrogen production

KW - Multifuel processor

KW - Oxygenates

KW - OXIDATION

KW - DIMETHOXYMETHANE

KW - formic acid decomposition

KW - COPPER

KW - CO

KW - hydrogen production

KW - CuO-CeO2/gamma-Al2O3

KW - oxygenates

KW - CUO/CEO2

KW - fuel cell

KW - PD

KW - multifuel processor

KW - copper catalyst

KW - CuO-CeO2/γ-Al2O3

UR - http://www.scopus.com/inward/record.url?scp=85072542374&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/ae24d536-20ae-38bf-9e24-94430b7b25c5/

U2 - 10.3390/en12183577

DO - 10.3390/en12183577

M3 - Article

AN - SCOPUS:85072542374

VL - 12

JO - Energies

JF - Energies

SN - 1996-1073

IS - 18

M1 - 3577

ER -

ID: 21610116