Результаты исследований: Научные публикации в периодических изданиях › статья по материалам конференции › Рецензирование
Preparation and study of morphology of mesoporous anodic films grown on tin foil. / Vasilieva, T. A.; Uvarov, N. F.; Bokhonov, B. B.
в: Materials Today: Proceedings, Том 25, 01.10.2019, стр. 401-404.Результаты исследований: Научные публикации в периодических изданиях › статья по материалам конференции › Рецензирование
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TY - JOUR
T1 - Preparation and study of morphology of mesoporous anodic films grown on tin foil
AU - Vasilieva, T. A.
AU - Uvarov, N. F.
AU - Bokhonov, B. B.
PY - 2019/10/1
Y1 - 2019/10/1
N2 - Mesoporous anodic layers were obtained on high-purity tin foils in electrolyte of two types: 0.3 M oxalic acid and 1 M NaOH in various anodizing modes. It was demonstrated that in both cases at low voltages below 4 V barrier films form. In acidic electrolyte the formation of tin (II) oxalate was observed whereas in basic electrolytes SnO2·nH2O seems to be formed. At intermediate voltage values from 4 to 8 V mesoporous films may be obtained with average size of pores of 20-40 nm, mesopores are rather uniformly distributed along the surface. It was found that in contrast to alumina anode films no linear dependency between pore diameter and voltage was observed at anodizing of tin foil. At voltages above 8 V and/or long-term anodization the film cracks and the film split to separate islands.
AB - Mesoporous anodic layers were obtained on high-purity tin foils in electrolyte of two types: 0.3 M oxalic acid and 1 M NaOH in various anodizing modes. It was demonstrated that in both cases at low voltages below 4 V barrier films form. In acidic electrolyte the formation of tin (II) oxalate was observed whereas in basic electrolytes SnO2·nH2O seems to be formed. At intermediate voltage values from 4 to 8 V mesoporous films may be obtained with average size of pores of 20-40 nm, mesopores are rather uniformly distributed along the surface. It was found that in contrast to alumina anode films no linear dependency between pore diameter and voltage was observed at anodizing of tin foil. At voltages above 8 V and/or long-term anodization the film cracks and the film split to separate islands.
KW - Anodic films
KW - Anodizing of tin
KW - Barrier layer tin(II) oxalate
KW - Effect of voltage
KW - Mesoporous layer on the tin surface
KW - OXIDATION
KW - ANODIZATION
KW - OXIDE LAYERS
KW - SNO2
UR - http://www.scopus.com/inward/record.url?scp=85086941371&partnerID=8YFLogxK
U2 - 10.1016/j.matpr.2019.12.118
DO - 10.1016/j.matpr.2019.12.118
M3 - Conference article
AN - SCOPUS:85086941371
VL - 25
SP - 401
EP - 404
JO - Materials Today: Proceedings
JF - Materials Today: Proceedings
SN - 2214-7853
T2 - 3rd All-Russian Conference, with International Participation Hot Topics of Solid State Chemistry : From New Ideas to New Materials, HTSSC 2019
Y2 - 1 October 2019 through 5 October 2019
ER -
ID: 24613496