Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Porous nickel-based catalysts for tri-reforming of methane to synthesis gas: Catalytic activity. / Fedorova, Z. A.; Danilova, M. M.; Zaikovskii, V. I.
в: Materials Letters, Том 261, 127087, 15.02.2020.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Porous nickel-based catalysts for tri-reforming of methane to synthesis gas: Catalytic activity
AU - Fedorova, Z. A.
AU - Danilova, M. M.
AU - Zaikovskii, V. I.
PY - 2020/2/15
Y1 - 2020/2/15
N2 - The supported nickel catalysts based on porous nickel ribbon with MgO underlayer were tested in tri-reforming of methane to synthesis gas (1 atm, 750 °C, CH4/CO2/H2O/O2/N2 = 24/18/18/3,5/36,5, GHSV = 62.5 L/gh). The predominant part of the supported nickel particles in the used catalysts remain in the state of dispersed crystallites epitaxially bound to MgO. Besides, highly dispersed nickel crystallites (2–3 nm) epitaxially bound to MgO also appear. These catalysts showed stable activity throughout the test period (9 h); after the reaction no carbon formation was observed. The resistance of these catalysts to carbon formation was attributed both to the formation of nickel crystallites epitaxially bound to MgO and to the formation of the MgO underlayer that covers the nickel ribbon and prevents its contact with the reaction medium.
AB - The supported nickel catalysts based on porous nickel ribbon with MgO underlayer were tested in tri-reforming of methane to synthesis gas (1 atm, 750 °C, CH4/CO2/H2O/O2/N2 = 24/18/18/3,5/36,5, GHSV = 62.5 L/gh). The predominant part of the supported nickel particles in the used catalysts remain in the state of dispersed crystallites epitaxially bound to MgO. Besides, highly dispersed nickel crystallites (2–3 nm) epitaxially bound to MgO also appear. These catalysts showed stable activity throughout the test period (9 h); after the reaction no carbon formation was observed. The resistance of these catalysts to carbon formation was attributed both to the formation of nickel crystallites epitaxially bound to MgO and to the formation of the MgO underlayer that covers the nickel ribbon and prevents its contact with the reaction medium.
KW - Nickel catalysts
KW - Solid solution
KW - Tri-reforming
KW - HEAT-TRANSFER
KW - PERFORMANCE
KW - CO2
KW - STEAM
KW - SUPPORT
KW - MGO
KW - PARTIAL OXIDATION
KW - CARBON-DIOXIDE
KW - SYNGAS
KW - NI CATALYSTS
UR - http://www.scopus.com/inward/record.url?scp=85076037256&partnerID=8YFLogxK
U2 - 10.1016/j.matlet.2019.127087
DO - 10.1016/j.matlet.2019.127087
M3 - Article
AN - SCOPUS:85076037256
VL - 261
JO - Materials Letters
JF - Materials Letters
SN - 0167-577X
M1 - 127087
ER -
ID: 23055778