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Porous nickel-based catalysts for tri-reforming of methane to synthesis gas: Catalytic activity. / Fedorova, Z. A.; Danilova, M. M.; Zaikovskii, V. I.

In: Materials Letters, Vol. 261, 127087, 15.02.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Fedorova, ZA, Danilova, MM & Zaikovskii, VI 2020, 'Porous nickel-based catalysts for tri-reforming of methane to synthesis gas: Catalytic activity', Materials Letters, vol. 261, 127087. https://doi.org/10.1016/j.matlet.2019.127087

APA

Fedorova, Z. A., Danilova, M. M., & Zaikovskii, V. I. (2020). Porous nickel-based catalysts for tri-reforming of methane to synthesis gas: Catalytic activity. Materials Letters, 261, [127087]. https://doi.org/10.1016/j.matlet.2019.127087

Vancouver

Fedorova ZA, Danilova MM, Zaikovskii VI. Porous nickel-based catalysts for tri-reforming of methane to synthesis gas: Catalytic activity. Materials Letters. 2020 Feb 15;261:127087. doi: 10.1016/j.matlet.2019.127087

Author

Fedorova, Z. A. ; Danilova, M. M. ; Zaikovskii, V. I. / Porous nickel-based catalysts for tri-reforming of methane to synthesis gas: Catalytic activity. In: Materials Letters. 2020 ; Vol. 261.

BibTeX

@article{c3ffdd28ee344864ac7130fe118316f2,
title = "Porous nickel-based catalysts for tri-reforming of methane to synthesis gas: Catalytic activity",
abstract = "The supported nickel catalysts based on porous nickel ribbon with MgO underlayer were tested in tri-reforming of methane to synthesis gas (1 atm, 750 °C, CH4/CO2/H2O/O2/N2 = 24/18/18/3,5/36,5, GHSV = 62.5 L/gh). The predominant part of the supported nickel particles in the used catalysts remain in the state of dispersed crystallites epitaxially bound to MgO. Besides, highly dispersed nickel crystallites (2–3 nm) epitaxially bound to MgO also appear. These catalysts showed stable activity throughout the test period (9 h); after the reaction no carbon formation was observed. The resistance of these catalysts to carbon formation was attributed both to the formation of nickel crystallites epitaxially bound to MgO and to the formation of the MgO underlayer that covers the nickel ribbon and prevents its contact with the reaction medium.",
keywords = "Nickel catalysts, Solid solution, Tri-reforming, HEAT-TRANSFER, PERFORMANCE, CO2, STEAM, SUPPORT, MGO, PARTIAL OXIDATION, CARBON-DIOXIDE, SYNGAS, NI CATALYSTS",
author = "Fedorova, {Z. A.} and Danilova, {M. M.} and Zaikovskii, {V. I.}",
year = "2020",
month = feb,
day = "15",
doi = "10.1016/j.matlet.2019.127087",
language = "English",
volume = "261",
journal = "Materials Letters",
issn = "0167-577X",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Porous nickel-based catalysts for tri-reforming of methane to synthesis gas: Catalytic activity

AU - Fedorova, Z. A.

AU - Danilova, M. M.

AU - Zaikovskii, V. I.

PY - 2020/2/15

Y1 - 2020/2/15

N2 - The supported nickel catalysts based on porous nickel ribbon with MgO underlayer were tested in tri-reforming of methane to synthesis gas (1 atm, 750 °C, CH4/CO2/H2O/O2/N2 = 24/18/18/3,5/36,5, GHSV = 62.5 L/gh). The predominant part of the supported nickel particles in the used catalysts remain in the state of dispersed crystallites epitaxially bound to MgO. Besides, highly dispersed nickel crystallites (2–3 nm) epitaxially bound to MgO also appear. These catalysts showed stable activity throughout the test period (9 h); after the reaction no carbon formation was observed. The resistance of these catalysts to carbon formation was attributed both to the formation of nickel crystallites epitaxially bound to MgO and to the formation of the MgO underlayer that covers the nickel ribbon and prevents its contact with the reaction medium.

AB - The supported nickel catalysts based on porous nickel ribbon with MgO underlayer were tested in tri-reforming of methane to synthesis gas (1 atm, 750 °C, CH4/CO2/H2O/O2/N2 = 24/18/18/3,5/36,5, GHSV = 62.5 L/gh). The predominant part of the supported nickel particles in the used catalysts remain in the state of dispersed crystallites epitaxially bound to MgO. Besides, highly dispersed nickel crystallites (2–3 nm) epitaxially bound to MgO also appear. These catalysts showed stable activity throughout the test period (9 h); after the reaction no carbon formation was observed. The resistance of these catalysts to carbon formation was attributed both to the formation of nickel crystallites epitaxially bound to MgO and to the formation of the MgO underlayer that covers the nickel ribbon and prevents its contact with the reaction medium.

KW - Nickel catalysts

KW - Solid solution

KW - Tri-reforming

KW - HEAT-TRANSFER

KW - PERFORMANCE

KW - CO2

KW - STEAM

KW - SUPPORT

KW - MGO

KW - PARTIAL OXIDATION

KW - CARBON-DIOXIDE

KW - SYNGAS

KW - NI CATALYSTS

UR - http://www.scopus.com/inward/record.url?scp=85076037256&partnerID=8YFLogxK

U2 - 10.1016/j.matlet.2019.127087

DO - 10.1016/j.matlet.2019.127087

M3 - Article

AN - SCOPUS:85076037256

VL - 261

JO - Materials Letters

JF - Materials Letters

SN - 0167-577X

M1 - 127087

ER -

ID: 23055778