Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation. / Kaletina, Polina M.; Vinogradov, Andrey S.; Shaparenko, Nikita O. и др.
в: Journal of Polymer Science, Том 61, № 20, 10.2023, стр. 2462-2474.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation
AU - Kaletina, Polina M.
AU - Vinogradov, Andrey S.
AU - Shaparenko, Nikita O.
AU - Parkhomenko, Dmitriy A.
AU - Shundrina, Inna K.
AU - Mezhenkova, Tatyana V.
AU - Bagryanskaya, Elena G.
N1 - This work was supported by the Ministry of Science and Higher Education of the Russian Federation (state registration No. 122040800265‐0). The authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements. The English language was corrected by shevchuk-editing.com. Публикация для корректировки.
PY - 2023/10
Y1 - 2023/10
N2 - In this study, we report the synthesis of a new fluorinated vinyl monomer, that is, pentafluorophenyl vinyl ketone [1-(pentafluorophenyl)prop-2-en-1-one], its radical polymerization and copolymerization with styrene, methyl vinyl ketone, or phenyl vinyl ketone. The obtained homo- and co-polymers were subjected to thermal analysis, contact angle measurement, and an assay of resistance to UV irradiation. The results showed that the poly(pentafluorophenyl vinyl ketone) has a slightly greater contact angle and a lower temperature of the maximum decomposition rate when compared to the nonfluorinated analog: poly(phenyl vinyl ketone).
AB - In this study, we report the synthesis of a new fluorinated vinyl monomer, that is, pentafluorophenyl vinyl ketone [1-(pentafluorophenyl)prop-2-en-1-one], its radical polymerization and copolymerization with styrene, methyl vinyl ketone, or phenyl vinyl ketone. The obtained homo- and co-polymers were subjected to thermal analysis, contact angle measurement, and an assay of resistance to UV irradiation. The results showed that the poly(pentafluorophenyl vinyl ketone) has a slightly greater contact angle and a lower temperature of the maximum decomposition rate when compared to the nonfluorinated analog: poly(phenyl vinyl ketone).
KW - copolymerization
KW - fluoropolymers
KW - photodegradation
KW - poly(vinyl ketone)s
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85165367121&origin=inward&txGid=722c85b285db810b7099f96ccc1605e0
UR - https://www.mendeley.com/catalogue/d6e8405b-7486-3c0d-9329-9a7b8800d425/
U2 - 10.1002/pol.20230185
DO - 10.1002/pol.20230185
M3 - Article
VL - 61
SP - 2462
EP - 2474
JO - Journal of Polymer Science
JF - Journal of Polymer Science
SN - 2642-4169
IS - 20
ER -
ID: 59547295