Standard

Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation. / Kaletina, Polina M.; Vinogradov, Andrey S.; Shaparenko, Nikita O. et al.

In: Journal of Polymer Science, Vol. 61, No. 20, 10.2023, p. 2462-2474.

Research output: Contribution to journal › Article › peer-review

Harvard

Kaletina, PM, Vinogradov, AS, Shaparenko, NO, Parkhomenko, DA, Shundrina, IK, Mezhenkova, TV & Bagryanskaya, EG 2023, 'Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation', Journal of Polymer Science, vol. 61, no. 20, pp. 2462-2474. https://doi.org/10.1002/pol.20230185

APA

Kaletina, P. M., Vinogradov, A. S., Shaparenko, N. O., Parkhomenko, D. A., Shundrina, I. K., Mezhenkova, T. V., & Bagryanskaya, E. G. (2023). Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation. Journal of Polymer Science, 61(20), 2462-2474. https://doi.org/10.1002/pol.20230185

Vancouver

Kaletina PM, Vinogradov AS, Shaparenko NO, Parkhomenko DA, Shundrina IK, Mezhenkova TV et al. Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation. Journal of Polymer Science. 2023 Oct;61(20):2462-2474. doi: 10.1002/pol.20230185

Author

Kaletina, Polina M. ; Vinogradov, Andrey S. ; Shaparenko, Nikita O. et al. / Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation. In: Journal of Polymer Science. 2023 ; Vol. 61, No. 20. pp. 2462-2474.

BibTeX

@article{78438baddebe4a459ff8503e50ebd255,
title = "Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation",
abstract = "In this study, we report the synthesis of a new fluorinated vinyl monomer, that is, pentafluorophenyl vinyl ketone [1-(pentafluorophenyl)prop-2-en-1-one], its radical polymerization and copolymerization with styrene, methyl vinyl ketone, or phenyl vinyl ketone. The obtained homo- and co-polymers were subjected to thermal analysis, contact angle measurement, and an assay of resistance to UV irradiation. The results showed that the poly(pentafluorophenyl vinyl ketone) has a slightly greater contact angle and a lower temperature of the maximum decomposition rate when compared to the nonfluorinated analog: poly(phenyl vinyl ketone).",
keywords = "copolymerization, fluoropolymers, photodegradation, poly(vinyl ketone)s",
author = "Kaletina, {Polina M.} and Vinogradov, {Andrey S.} and Shaparenko, {Nikita O.} and Parkhomenko, {Dmitriy A.} and Shundrina, {Inna K.} and Mezhenkova, {Tatyana V.} and Bagryanskaya, {Elena G.}",
note = "This work was supported by the Ministry of Science and Higher Education of the Russian Federation (state registration No. 122040800265‐0). The authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements. The English language was corrected by shevchuk-editing.com. Публикация для корректировки.",
year = "2023",
month = oct,
doi = "10.1002/pol.20230185",
language = "English",
volume = "61",
pages = "2462--2474",
journal = "Journal of Polymer Science",
issn = "2642-4169",
publisher = "John Wiley & Sons Inc.",
number = "20",

}

RIS

TY - JOUR

T1 - Pentafluorophenyl vinyl ketone: Synthesis, radical polymerization, copolymerization, and polymer degradation under ultra-violet irradiation

AU - Kaletina, Polina M.

AU - Vinogradov, Andrey S.

AU - Shaparenko, Nikita O.

AU - Parkhomenko, Dmitriy A.

AU - Shundrina, Inna K.

AU - Mezhenkova, Tatyana V.

AU - Bagryanskaya, Elena G.

N1 - This work was supported by the Ministry of Science and Higher Education of the Russian Federation (state registration No. 122040800265‐0). The authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements. The English language was corrected by shevchuk-editing.com. Публикация для корректировки.

PY - 2023/10

Y1 - 2023/10

N2 - In this study, we report the synthesis of a new fluorinated vinyl monomer, that is, pentafluorophenyl vinyl ketone [1-(pentafluorophenyl)prop-2-en-1-one], its radical polymerization and copolymerization with styrene, methyl vinyl ketone, or phenyl vinyl ketone. The obtained homo- and co-polymers were subjected to thermal analysis, contact angle measurement, and an assay of resistance to UV irradiation. The results showed that the poly(pentafluorophenyl vinyl ketone) has a slightly greater contact angle and a lower temperature of the maximum decomposition rate when compared to the nonfluorinated analog: poly(phenyl vinyl ketone).

AB - In this study, we report the synthesis of a new fluorinated vinyl monomer, that is, pentafluorophenyl vinyl ketone [1-(pentafluorophenyl)prop-2-en-1-one], its radical polymerization and copolymerization with styrene, methyl vinyl ketone, or phenyl vinyl ketone. The obtained homo- and co-polymers were subjected to thermal analysis, contact angle measurement, and an assay of resistance to UV irradiation. The results showed that the poly(pentafluorophenyl vinyl ketone) has a slightly greater contact angle and a lower temperature of the maximum decomposition rate when compared to the nonfluorinated analog: poly(phenyl vinyl ketone).

KW - copolymerization

KW - fluoropolymers

KW - photodegradation

KW - poly(vinyl ketone)s

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85165367121&origin=inward&txGid=722c85b285db810b7099f96ccc1605e0

UR - https://www.mendeley.com/catalogue/d6e8405b-7486-3c0d-9329-9a7b8800d425/

U2 - 10.1002/pol.20230185

DO - 10.1002/pol.20230185

M3 - Article

VL - 61

SP - 2462

EP - 2474

JO - Journal of Polymer Science

JF - Journal of Polymer Science

SN - 2642-4169

IS - 20

ER -

ID: 59547295