Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Optical Phonon Spectrum of the Ge2Sb2Te5 Single Crystal. / Talochkin, A. B.; Kokh, K. A.; Tereshchenko, O. E.
в: JETP Letters, Том 113, № 10, 05.2021, стр. 651-656.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Optical Phonon Spectrum of the Ge2Sb2Te5 Single Crystal
AU - Talochkin, A. B.
AU - Kokh, K. A.
AU - Tereshchenko, O. E.
N1 - Publisher Copyright: © 2021, Pleiades Publishing, Inc. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2021/5
Y1 - 2021/5
N2 - Raman scattering by optical phonons of the Ge2Sb2Te5 single crystal grown by the Bridgman method is studied for the first time. Another method for obtaining this compound based on annealing of the amorphous state and used in numerous previous studies leads to the formation of various defects which significantly affect the optical phonons spectrum. This hampers the identification of observed phonon spectra. The use of the bulk Ge2Sb2Te5 single crystal has made it possible to exclude the effect of lattice defects and to reveal new features of the phonon spectrum associated with the lattice structure. Broad features typical of the amorphous state and narrow phonon lines of the crystal state are observed in the spectra. It has been shown that the former component is due to disorder appearing because of the mixing of Ge and Sb atoms in corresponding layers of the lattice. Moreover, there are optical phonons whose frequencies are independent of this mi-xing in view of the specificity of their eigenvectors. These modes are manifested in spectra as intense narrow lines.
AB - Raman scattering by optical phonons of the Ge2Sb2Te5 single crystal grown by the Bridgman method is studied for the first time. Another method for obtaining this compound based on annealing of the amorphous state and used in numerous previous studies leads to the formation of various defects which significantly affect the optical phonons spectrum. This hampers the identification of observed phonon spectra. The use of the bulk Ge2Sb2Te5 single crystal has made it possible to exclude the effect of lattice defects and to reveal new features of the phonon spectrum associated with the lattice structure. Broad features typical of the amorphous state and narrow phonon lines of the crystal state are observed in the spectra. It has been shown that the former component is due to disorder appearing because of the mixing of Ge and Sb atoms in corresponding layers of the lattice. Moreover, there are optical phonons whose frequencies are independent of this mi-xing in view of the specificity of their eigenvectors. These modes are manifested in spectra as intense narrow lines.
UR - http://www.scopus.com/inward/record.url?scp=85110966478&partnerID=8YFLogxK
U2 - 10.1134/S002136402110012X
DO - 10.1134/S002136402110012X
M3 - Article
AN - SCOPUS:85110966478
VL - 113
SP - 651
EP - 656
JO - JETP Letters
JF - JETP Letters
SN - 0021-3640
IS - 10
ER -
ID: 29232886