Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Novel Anthrathiophene-Based Small Molecules as Donor Material for Organic Photovoltaics : Synthesis and Light-Induced EPR Study. / Shatrova, Alexandra A.; Baranov, Denis S.; Uvarov, Mikhail N. и др.
в: Zeitschrift fur Physikalische Chemie, Том 231, № 2, 01.02.2017, стр. 425-438.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Novel Anthrathiophene-Based Small Molecules as Donor Material for Organic Photovoltaics
T2 - Synthesis and Light-Induced EPR Study
AU - Shatrova, Alexandra A.
AU - Baranov, Denis S.
AU - Uvarov, Mikhail N.
AU - Kazantsev, Maxim S.
AU - Glebov, Evgeni M.
AU - Fadeev, Dmitry S.
AU - Kulik, Leonid V.
PY - 2017/2/1
Y1 - 2017/2/1
N2 - A novel anthrathiophene-based compound, 1,4-bis((5-(6,11-dioxoanthra[2,1-b]thiophene-2-yl)thien-2-yl)ethynyl)-2,5-bis(octyloxy)benzene, was synthesized and characterized. The optical absorption spectrum of the synthesized compound in film is strongly red-shifted as compared to the solution spectrum. The energies of frontier orbitals measured by cyclic voltammetry show that this compound can act as electron donor in a composite with the widely used fullerene derivative PCBM. This is confirmed by light-induced electron transfer from it to PCBM evidenced from light-induced EPR spectroscopy. The spectroscopic data suggest that anthrathiophene is a promising platform for synthesis of small-molecular electron donors for organic solar cells.
AB - A novel anthrathiophene-based compound, 1,4-bis((5-(6,11-dioxoanthra[2,1-b]thiophene-2-yl)thien-2-yl)ethynyl)-2,5-bis(octyloxy)benzene, was synthesized and characterized. The optical absorption spectrum of the synthesized compound in film is strongly red-shifted as compared to the solution spectrum. The energies of frontier orbitals measured by cyclic voltammetry show that this compound can act as electron donor in a composite with the widely used fullerene derivative PCBM. This is confirmed by light-induced electron transfer from it to PCBM evidenced from light-induced EPR spectroscopy. The spectroscopic data suggest that anthrathiophene is a promising platform for synthesis of small-molecular electron donors for organic solar cells.
KW - anthrathiophene
KW - charge transfer
KW - electrochemistry
KW - EPR
KW - luminescence
KW - organic photovoltaics
KW - synthesis
UR - http://www.scopus.com/inward/record.url?scp=85012215299&partnerID=8YFLogxK
U2 - 10.1515/zpch-2016-0832
DO - 10.1515/zpch-2016-0832
M3 - Article
AN - SCOPUS:85012215299
VL - 231
SP - 425
EP - 438
JO - Zeitschrift fur Physikalische Chemie
JF - Zeitschrift fur Physikalische Chemie
SN - 0942-9352
IS - 2
ER -
ID: 9052915