Standard

Novel Anthrathiophene-Based Small Molecules as Donor Material for Organic Photovoltaics : Synthesis and Light-Induced EPR Study. / Shatrova, Alexandra A.; Baranov, Denis S.; Uvarov, Mikhail N. et al.

In: Zeitschrift fur Physikalische Chemie, Vol. 231, No. 2, 01.02.2017, p. 425-438.

Research output: Contribution to journal › Article › peer-review

Harvard

Shatrova, AA, Baranov, DS, Uvarov, MN, Kazantsev, MS, Glebov, EM, Fadeev, DS & Kulik, LV 2017, 'Novel Anthrathiophene-Based Small Molecules as Donor Material for Organic Photovoltaics: Synthesis and Light-Induced EPR Study', Zeitschrift fur Physikalische Chemie, vol. 231, no. 2, pp. 425-438. https://doi.org/10.1515/zpch-2016-0832

APA

Shatrova, A. A., Baranov, D. S., Uvarov, M. N., Kazantsev, M. S., Glebov, E. M., Fadeev, D. S., & Kulik, L. V. (2017). Novel Anthrathiophene-Based Small Molecules as Donor Material for Organic Photovoltaics: Synthesis and Light-Induced EPR Study. Zeitschrift fur Physikalische Chemie, 231(2), 425-438. https://doi.org/10.1515/zpch-2016-0832

Vancouver

Shatrova AA, Baranov DS, Uvarov MN, Kazantsev MS, Glebov EM, Fadeev DS et al. Novel Anthrathiophene-Based Small Molecules as Donor Material for Organic Photovoltaics: Synthesis and Light-Induced EPR Study. Zeitschrift fur Physikalische Chemie. 2017 Feb 1;231(2):425-438. doi: 10.1515/zpch-2016-0832

Author

Shatrova, Alexandra A. ; Baranov, Denis S. ; Uvarov, Mikhail N. et al. / Novel Anthrathiophene-Based Small Molecules as Donor Material for Organic Photovoltaics : Synthesis and Light-Induced EPR Study. In: Zeitschrift fur Physikalische Chemie. 2017 ; Vol. 231, No. 2. pp. 425-438.

BibTeX

@article{f0b576223f29428a91dc187c26e725ad,
title = "Novel Anthrathiophene-Based Small Molecules as Donor Material for Organic Photovoltaics: Synthesis and Light-Induced EPR Study",
abstract = "A novel anthrathiophene-based compound, 1,4-bis((5-(6,11-dioxoanthra[2,1-b]thiophene-2-yl)thien-2-yl)ethynyl)-2,5-bis(octyloxy)benzene, was synthesized and characterized. The optical absorption spectrum of the synthesized compound in film is strongly red-shifted as compared to the solution spectrum. The energies of frontier orbitals measured by cyclic voltammetry show that this compound can act as electron donor in a composite with the widely used fullerene derivative PCBM. This is confirmed by light-induced electron transfer from it to PCBM evidenced from light-induced EPR spectroscopy. The spectroscopic data suggest that anthrathiophene is a promising platform for synthesis of small-molecular electron donors for organic solar cells.",
keywords = "anthrathiophene, charge transfer, electrochemistry, EPR, luminescence, organic photovoltaics, synthesis",
author = "Shatrova, {Alexandra A.} and Baranov, {Denis S.} and Uvarov, {Mikhail N.} and Kazantsev, {Maxim S.} and Glebov, {Evgeni M.} and Fadeev, {Dmitry S.} and Kulik, {Leonid V.}",
year = "2017",
month = feb,
day = "1",
doi = "10.1515/zpch-2016-0832",
language = "English",
volume = "231",
pages = "425--438",
journal = "Zeitschrift fur Physikalische Chemie",
issn = "0942-9352",
publisher = "Walter de Gruyter GmbH",
number = "2",

}

RIS

TY - JOUR

T1 - Novel Anthrathiophene-Based Small Molecules as Donor Material for Organic Photovoltaics

T2 - Synthesis and Light-Induced EPR Study

AU - Shatrova, Alexandra A.

AU - Baranov, Denis S.

AU - Uvarov, Mikhail N.

AU - Kazantsev, Maxim S.

AU - Glebov, Evgeni M.

AU - Fadeev, Dmitry S.

AU - Kulik, Leonid V.

PY - 2017/2/1

Y1 - 2017/2/1

N2 - A novel anthrathiophene-based compound, 1,4-bis((5-(6,11-dioxoanthra[2,1-b]thiophene-2-yl)thien-2-yl)ethynyl)-2,5-bis(octyloxy)benzene, was synthesized and characterized. The optical absorption spectrum of the synthesized compound in film is strongly red-shifted as compared to the solution spectrum. The energies of frontier orbitals measured by cyclic voltammetry show that this compound can act as electron donor in a composite with the widely used fullerene derivative PCBM. This is confirmed by light-induced electron transfer from it to PCBM evidenced from light-induced EPR spectroscopy. The spectroscopic data suggest that anthrathiophene is a promising platform for synthesis of small-molecular electron donors for organic solar cells.

AB - A novel anthrathiophene-based compound, 1,4-bis((5-(6,11-dioxoanthra[2,1-b]thiophene-2-yl)thien-2-yl)ethynyl)-2,5-bis(octyloxy)benzene, was synthesized and characterized. The optical absorption spectrum of the synthesized compound in film is strongly red-shifted as compared to the solution spectrum. The energies of frontier orbitals measured by cyclic voltammetry show that this compound can act as electron donor in a composite with the widely used fullerene derivative PCBM. This is confirmed by light-induced electron transfer from it to PCBM evidenced from light-induced EPR spectroscopy. The spectroscopic data suggest that anthrathiophene is a promising platform for synthesis of small-molecular electron donors for organic solar cells.

KW - anthrathiophene

KW - charge transfer

KW - electrochemistry

KW - EPR

KW - luminescence

KW - organic photovoltaics

KW - synthesis

UR - http://www.scopus.com/inward/record.url?scp=85012215299&partnerID=8YFLogxK

U2 - 10.1515/zpch-2016-0832

DO - 10.1515/zpch-2016-0832

M3 - Article

AN - SCOPUS:85012215299

VL - 231

SP - 425

EP - 438

JO - Zeitschrift fur Physikalische Chemie

JF - Zeitschrift fur Physikalische Chemie

SN - 0942-9352

IS - 2

ER -

ID: 9052915