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Luminescent coordination polymers based on [{Mo6I8}(CN)6]2− clusters and Ag(i) complexes: structural design of bright red to NIR scintillating materials. / Litvinova, Yulia M.; Subbotin, Yaromir A.; Stass, Dmitri V. и др.
в: Journal of Materials Chemistry C, Том 14, № 37, 31.07.2026.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Luminescent coordination polymers based on [{Mo6I8}(CN)6]2− clusters and Ag(i) complexes: structural design of bright red to NIR scintillating materials
AU - Litvinova, Yulia M.
AU - Subbotin, Yaromir A.
AU - Stass, Dmitri V.
AU - Metlin, Mikhail T.
AU - Taydakov, Ilya V.
AU - Ryzhikov, Maxim R.
AU - Yarovoy, Spartak S.
AU - Sukhikh, Taisiya S.
AU - Mironov, Yuri V.
AU - Tarasov, Alexey B.
AU - Brylev, Konstantin A.
AU - Gaifulin, Yakov M.
PY - 2026/7/31
Y1 - 2026/7/31
N2 - In this work, a series of coordination polymers based on the [{Mo6I8}(CN)6]2− cluster units coordinated by silver phosphine complexes were studied. Three new polymeric compounds, [{Ag2(dppe)3}{Mo6I8}(CN)6] (1), [{Ag2(dppe)2}{Mo6I8}(CN)6] (2), and [{Ag2(dppp)2}{Mo6I8}(CN)6] (3), where dppe = 1,2-bis(diphenylphosphino)ethane and dppp = 1,3-bis(diphenylphosphino)propane, were synthesized solvothermally, displaying chain (1 and 2) and layered (3) structures. All compounds exhibit high hydrolytic and thermal stability. At room temperature, their photoluminescence quantum yields are 0.27, 0.19, and 0.28, with corresponding X-ray-excited luminescence light yields of 13 360, 9843, and 22 265 ph per MeV for 1–3, respectively. Dispersing the polymers in ethylene-vinyl acetate (EVA) yielded composite materials suitable for use as X-ray scintillation screens, with enhanced X-ray emission efficiency (up to 30 348 ph per MeV) and spatial resolution (up to 7.5 line pairs per mm). Quantum-chemical calculations correlate the luminescence properties with structural features, specifically the presence of argentophilic contacts. The absence of such contacts appears to promote charge transfer, thereby enhancing emission. This combination of structural variation and composite engineering enabled the development of new bright broadband red/NIR scintillators based on the [{Mo6I8}(CN)6]2− cluster.
AB - In this work, a series of coordination polymers based on the [{Mo6I8}(CN)6]2− cluster units coordinated by silver phosphine complexes were studied. Three new polymeric compounds, [{Ag2(dppe)3}{Mo6I8}(CN)6] (1), [{Ag2(dppe)2}{Mo6I8}(CN)6] (2), and [{Ag2(dppp)2}{Mo6I8}(CN)6] (3), where dppe = 1,2-bis(diphenylphosphino)ethane and dppp = 1,3-bis(diphenylphosphino)propane, were synthesized solvothermally, displaying chain (1 and 2) and layered (3) structures. All compounds exhibit high hydrolytic and thermal stability. At room temperature, their photoluminescence quantum yields are 0.27, 0.19, and 0.28, with corresponding X-ray-excited luminescence light yields of 13 360, 9843, and 22 265 ph per MeV for 1–3, respectively. Dispersing the polymers in ethylene-vinyl acetate (EVA) yielded composite materials suitable for use as X-ray scintillation screens, with enhanced X-ray emission efficiency (up to 30 348 ph per MeV) and spatial resolution (up to 7.5 line pairs per mm). Quantum-chemical calculations correlate the luminescence properties with structural features, specifically the presence of argentophilic contacts. The absence of such contacts appears to promote charge transfer, thereby enhancing emission. This combination of structural variation and composite engineering enabled the development of new bright broadband red/NIR scintillators based on the [{Mo6I8}(CN)6]2− cluster.
UR - https://www.scopus.com/pages/publications/105047901699
UR - https://www.mendeley.com/catalogue/13dba4d4-77d1-353a-8a22-753316e53625/
U2 - 10.1039/d6tc01735e
DO - 10.1039/d6tc01735e
M3 - Article
VL - 14
JO - Journal of Materials Chemistry C
JF - Journal of Materials Chemistry C
SN - 2050-7526
IS - 37
ER -
ID: 84325612