Low-Temperature Partial Oxidation of Dimethyl Ether to Hydrogen-Rich Gas over CuO–CeO2/γ-Al2O3 Catalysts for Fuel Cell Supply

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Low-Temperature Partial Oxidation of Dimethyl Ether to Hydrogen-Rich Gas over CuO–CeO₂/γ-Al₂O₃ Catalysts for Fuel Cell Supply. / Badmaev, S. D.; Akhmetov, N. O.; Pechenkin, A. A. и др.

в: Doklady Physical Chemistry, Том 487, № 2, 01.08.2019, стр. 95-98.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{078e3c96702f406cb366bcade96ae30c,

title = "Low-Temperature Partial Oxidation of Dimethyl Ether to Hydrogen-Rich Gas over CuO–CeO2/γ-Al2O3 Catalysts for Fuel Cell Supply",

abstract = "The CuO–CeO2/γ-Al2O3 systems have good prospects as catalysts for partial oxidation of dimethyl ether (DME) with air to give hydrogen-rich gas for fuel cell feeding. At atmospheric pressure, temperature of ~350°C, and reaction mixture flow rate of 7 L/(gcat h) and the DME : O2 : N2 molar ratio of 1 : 1 : 4 (DME : air = 1 : 5), the catalysts provide complete DME conversion to hydrogen-rich gas with a low content of CH4 (≤0.8 mol %) and H2 production rate of ~3.1 L/(gcat h).",

keywords = "METHANOL, STATE",

author = "Badmaev, {S. D.} and Akhmetov, {N. O.} and Pechenkin, {A. A.} and Sobyanin, {V. A.} and Parmon, {V. N.}",

note = "Funding Information: This work was supported by Ministry of Science and Higher Education of the Russian Federation (project no. AAAA-A17-117041710088-0). Publisher Copyright: {\textcopyright} 2019, Pleiades Publishing, Ltd. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",

year = "2019",

month = aug,

day = "1",

doi = "10.1134/S0012501619080013",

language = "English",

volume = "487",

pages = "95--98",

journal = "Doklady Physical Chemistry",

issn = "0012-5016",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "2",

}

RIS

TY - JOUR

T1 - Low-Temperature Partial Oxidation of Dimethyl Ether to Hydrogen-Rich Gas over CuO–CeO2/γ-Al2O3 Catalysts for Fuel Cell Supply

AU - Badmaev, S. D.

AU - Akhmetov, N. O.

AU - Pechenkin, A. A.

AU - Sobyanin, V. A.

AU - Parmon, V. N.

N1 - Funding Information: This work was supported by Ministry of Science and Higher Education of the Russian Federation (project no. AAAA-A17-117041710088-0). Publisher Copyright: © 2019, Pleiades Publishing, Ltd. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2019/8/1

Y1 - 2019/8/1

N2 - The CuO–CeO2/γ-Al2O3 systems have good prospects as catalysts for partial oxidation of dimethyl ether (DME) with air to give hydrogen-rich gas for fuel cell feeding. At atmospheric pressure, temperature of ~350°C, and reaction mixture flow rate of 7 L/(gcat h) and the DME : O2 : N2 molar ratio of 1 : 1 : 4 (DME : air = 1 : 5), the catalysts provide complete DME conversion to hydrogen-rich gas with a low content of CH4 (≤0.8 mol %) and H2 production rate of ~3.1 L/(gcat h).

AB - The CuO–CeO2/γ-Al2O3 systems have good prospects as catalysts for partial oxidation of dimethyl ether (DME) with air to give hydrogen-rich gas for fuel cell feeding. At atmospheric pressure, temperature of ~350°C, and reaction mixture flow rate of 7 L/(gcat h) and the DME : O2 : N2 molar ratio of 1 : 1 : 4 (DME : air = 1 : 5), the catalysts provide complete DME conversion to hydrogen-rich gas with a low content of CH4 (≤0.8 mol %) and H2 production rate of ~3.1 L/(gcat h).

KW - METHANOL

KW - STATE

UR - http://www.scopus.com/inward/record.url?scp=85073237489&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/bb2b6444-7fae-30f5-ad62-17bab1abcb21/

U2 - 10.1134/S0012501619080013

DO - 10.1134/S0012501619080013

M3 - Article

AN - SCOPUS:85073237489

VL - 487

SP - 95

EP - 98

JO - Doklady Physical Chemistry

JF - Doklady Physical Chemistry

SN - 0012-5016

IS - 2

ER -

ID: 21857767