Research output: Contribution to journal › Article › peer-review
Low-Temperature Partial Oxidation of Dimethyl Ether to Hydrogen-Rich Gas over CuO–CeO2/γ-Al2O3 Catalysts for Fuel Cell Supply. / Badmaev, S. D.; Akhmetov, N. O.; Pechenkin, A. A. et al.
In: Doklady Physical Chemistry, Vol. 487, No. 2, 01.08.2019, p. 95-98.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Low-Temperature Partial Oxidation of Dimethyl Ether to Hydrogen-Rich Gas over CuO–CeO2/γ-Al2O3 Catalysts for Fuel Cell Supply
AU - Badmaev, S. D.
AU - Akhmetov, N. O.
AU - Pechenkin, A. A.
AU - Sobyanin, V. A.
AU - Parmon, V. N.
N1 - Funding Information: This work was supported by Ministry of Science and Higher Education of the Russian Federation (project no. AAAA-A17-117041710088-0). Publisher Copyright: © 2019, Pleiades Publishing, Ltd. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.
PY - 2019/8/1
Y1 - 2019/8/1
N2 - The CuO–CeO2/γ-Al2O3 systems have good prospects as catalysts for partial oxidation of dimethyl ether (DME) with air to give hydrogen-rich gas for fuel cell feeding. At atmospheric pressure, temperature of ~350°C, and reaction mixture flow rate of 7 L/(gcat h) and the DME : O2 : N2 molar ratio of 1 : 1 : 4 (DME : air = 1 : 5), the catalysts provide complete DME conversion to hydrogen-rich gas with a low content of CH4 (≤0.8 mol %) and H2 production rate of ~3.1 L/(gcat h).
AB - The CuO–CeO2/γ-Al2O3 systems have good prospects as catalysts for partial oxidation of dimethyl ether (DME) with air to give hydrogen-rich gas for fuel cell feeding. At atmospheric pressure, temperature of ~350°C, and reaction mixture flow rate of 7 L/(gcat h) and the DME : O2 : N2 molar ratio of 1 : 1 : 4 (DME : air = 1 : 5), the catalysts provide complete DME conversion to hydrogen-rich gas with a low content of CH4 (≤0.8 mol %) and H2 production rate of ~3.1 L/(gcat h).
KW - METHANOL
KW - STATE
UR - http://www.scopus.com/inward/record.url?scp=85073237489&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/bb2b6444-7fae-30f5-ad62-17bab1abcb21/
U2 - 10.1134/S0012501619080013
DO - 10.1134/S0012501619080013
M3 - Article
AN - SCOPUS:85073237489
VL - 487
SP - 95
EP - 98
JO - Doklady Physical Chemistry
JF - Doklady Physical Chemistry
SN - 0012-5016
IS - 2
ER -
ID: 21857767