Kinetics and Composition of Gaseous Products of Pyrolysis of Organometallic Complexes of Nickel, Iron, and Copper with Inorganic Anions

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Kinetics and Composition of Gaseous Products of Pyrolysis of Organometallic Complexes of Nickel, Iron, and Copper with Inorganic Anions. / Shmakov, A. G.; Paletsky, A. A.; Netskina, O. V. и др.

в: Combustion, Explosion and Shock Waves, Том 60, № 1, 02.2024, стр. 25-41.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{800ba56bb8114a77ab6761847dfa1351,

title = "Kinetics and Composition of Gaseous Products of Pyrolysis of Organometallic Complexes of Nickel, Iron, and Copper with Inorganic Anions",

abstract = "Organometallic complexes of transition metals with inorganic anions are considered as promising precursors for the synthesis of nanoscale materials used in various applications including chemical catalysis. In this work, organometallic complexes of nickel, iron, and copper with imidazole as an organic ligand and the nitrate anion as an inorganic ligand were synthesized and characterized. The kinetic parameters of thermal decomposition of the synthesized organometallic complexes were determined by low heating-rate thermogravimetric analysis and high-speed dynamic mass spectrometric thermal analysis. The main gaseous products of thermal decomposition of the complexes under high-speed heating were identified. The chemical and phase compositions of condensed combustion products of the organometallic complexes in air were studied.",

keywords = "copper oxide, imidazole, iron oxide, nanoscale materials, nickel oxide, organometallic complexes, thermal decomposition kinetics",

author = "Shmakov, {A. G.} and Paletsky, {A. A.} and Netskina, {O. V.} and Dmitruk, {K. A.} and Komova, {O. V.} and Mukha, {S. A.}",

note = "This study was supported by the Ministry of Science and Higher Education of the Russian Federation (Project No. 075-15-2020-781).",

year = "2024",

month = feb,

doi = "10.1134/S0010508224010040",

language = "English",

volume = "60",

pages = "25--41",

journal = "Combustion, Explosion and Shock Waves",

issn = "0010-5082",

publisher = "Springer New York",

number = "1",

}

RIS

TY - JOUR

T1 - Kinetics and Composition of Gaseous Products of Pyrolysis of Organometallic Complexes of Nickel, Iron, and Copper with Inorganic Anions

AU - Shmakov, A. G.

AU - Paletsky, A. A.

AU - Netskina, O. V.

AU - Dmitruk, K. A.

AU - Komova, O. V.

AU - Mukha, S. A.

N1 - This study was supported by the Ministry of Science and Higher Education of the Russian Federation (Project No. 075-15-2020-781).

PY - 2024/2

Y1 - 2024/2

N2 - Organometallic complexes of transition metals with inorganic anions are considered as promising precursors for the synthesis of nanoscale materials used in various applications including chemical catalysis. In this work, organometallic complexes of nickel, iron, and copper with imidazole as an organic ligand and the nitrate anion as an inorganic ligand were synthesized and characterized. The kinetic parameters of thermal decomposition of the synthesized organometallic complexes were determined by low heating-rate thermogravimetric analysis and high-speed dynamic mass spectrometric thermal analysis. The main gaseous products of thermal decomposition of the complexes under high-speed heating were identified. The chemical and phase compositions of condensed combustion products of the organometallic complexes in air were studied.

AB - Organometallic complexes of transition metals with inorganic anions are considered as promising precursors for the synthesis of nanoscale materials used in various applications including chemical catalysis. In this work, organometallic complexes of nickel, iron, and copper with imidazole as an organic ligand and the nitrate anion as an inorganic ligand were synthesized and characterized. The kinetic parameters of thermal decomposition of the synthesized organometallic complexes were determined by low heating-rate thermogravimetric analysis and high-speed dynamic mass spectrometric thermal analysis. The main gaseous products of thermal decomposition of the complexes under high-speed heating were identified. The chemical and phase compositions of condensed combustion products of the organometallic complexes in air were studied.

KW - copper oxide

KW - imidazole

KW - iron oxide

KW - nanoscale materials

KW - nickel oxide

KW - organometallic complexes

KW - thermal decomposition kinetics

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85191072987&origin=inward&txGid=96461bfdd848bc1566fb2f00f61ca76d

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:001206349000012

UR - https://www.mendeley.com/catalogue/62aa95ae-34c6-3e39-8302-af93f6058023/

U2 - 10.1134/S0010508224010040

DO - 10.1134/S0010508224010040

M3 - Article

VL - 60

SP - 25

EP - 41

JO - Combustion, Explosion and Shock Waves

JF - Combustion, Explosion and Shock Waves

SN - 0010-5082

IS - 1

ER -

ID: 61200879