Research output: Contribution to journal › Article › peer-review
Kinetics and Composition of Gaseous Products of Pyrolysis of Organometallic Complexes of Nickel, Iron, and Copper with Inorganic Anions. / Shmakov, A. G.; Paletsky, A. A.; Netskina, O. V. et al.
In: Combustion, Explosion and Shock Waves, Vol. 60, No. 1, 02.2024, p. 25-41.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Kinetics and Composition of Gaseous Products of Pyrolysis of Organometallic Complexes of Nickel, Iron, and Copper with Inorganic Anions
AU - Shmakov, A. G.
AU - Paletsky, A. A.
AU - Netskina, O. V.
AU - Dmitruk, K. A.
AU - Komova, O. V.
AU - Mukha, S. A.
N1 - This study was supported by the Ministry of Science and Higher Education of the Russian Federation (Project No. 075-15-2020-781).
PY - 2024/2
Y1 - 2024/2
N2 - Organometallic complexes of transition metals with inorganic anions are considered as promising precursors for the synthesis of nanoscale materials used in various applications including chemical catalysis. In this work, organometallic complexes of nickel, iron, and copper with imidazole as an organic ligand and the nitrate anion as an inorganic ligand were synthesized and characterized. The kinetic parameters of thermal decomposition of the synthesized organometallic complexes were determined by low heating-rate thermogravimetric analysis and high-speed dynamic mass spectrometric thermal analysis. The main gaseous products of thermal decomposition of the complexes under high-speed heating were identified. The chemical and phase compositions of condensed combustion products of the organometallic complexes in air were studied.
AB - Organometallic complexes of transition metals with inorganic anions are considered as promising precursors for the synthesis of nanoscale materials used in various applications including chemical catalysis. In this work, organometallic complexes of nickel, iron, and copper with imidazole as an organic ligand and the nitrate anion as an inorganic ligand were synthesized and characterized. The kinetic parameters of thermal decomposition of the synthesized organometallic complexes were determined by low heating-rate thermogravimetric analysis and high-speed dynamic mass spectrometric thermal analysis. The main gaseous products of thermal decomposition of the complexes under high-speed heating were identified. The chemical and phase compositions of condensed combustion products of the organometallic complexes in air were studied.
KW - copper oxide
KW - imidazole
KW - iron oxide
KW - nanoscale materials
KW - nickel oxide
KW - organometallic complexes
KW - thermal decomposition kinetics
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85191072987&origin=inward&txGid=96461bfdd848bc1566fb2f00f61ca76d
UR - https://www.webofscience.com/wos/woscc/full-record/WOS:001206349000012
UR - https://www.mendeley.com/catalogue/62aa95ae-34c6-3e39-8302-af93f6058023/
U2 - 10.1134/S0010508224010040
DO - 10.1134/S0010508224010040
M3 - Article
VL - 60
SP - 25
EP - 41
JO - Combustion, Explosion and Shock Waves
JF - Combustion, Explosion and Shock Waves
SN - 0010-5082
IS - 1
ER -
ID: 61200879