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Investigation of Chloride Ion Substitution Equilibria in AuCl 4 with Ethylenediamine and 1,3-Diaminopropane Using Capillary Zone Electrophoresis. / Mironov, I. V.; Kharlamova, V. Yu; Kokovkin, V. V.

в: Russian Journal of Inorganic Chemistry, Том 63, № 1, 01.01.2018, стр. 134-139.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{f2cf59baaccc4330a11cbeb67b85e984,
title = "Investigation of Chloride Ion Substitution Equilibria in AuCl 4 − with Ethylenediamine and 1,3-Diaminopropane Using Capillary Zone Electrophoresis",
abstract = "Substitution of chloride ions in AuCl4 − with ethylenediamine (en) and propylenediamine (tn) is studied by capillary zone electrophoresis at I = 0.05 M and T = 25°C. The substitution constants are determined: AuenCl2 + + en = Auen2 3+ + 2Cl–, logK2 = 10.4; AuCl4 − + tn = AutnCl2 + + 2Cl–, logK1 = 16.1; AutnCl2 + + tn = Autn3+ 2 + 2Cl–, logK2 = 12.0.",
keywords = "PLANAR 4-CO-ORDINATE COMPLEXES, STABILITY-CONSTANTS, CHELATE LIGANDS, METAL-COMPLEXES, GOLD(III), DISPLACEMENT, KINETICS",
author = "Mironov, {I. V.} and Kharlamova, {V. Yu} and Kokovkin, {V. V.}",
year = "2018",
month = jan,
day = "1",
doi = "10.1134/S0036023618010126",
language = "English",
volume = "63",
pages = "134--139",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "1",

}

RIS

TY - JOUR

T1 - Investigation of Chloride Ion Substitution Equilibria in AuCl 4 − with Ethylenediamine and 1,3-Diaminopropane Using Capillary Zone Electrophoresis

AU - Mironov, I. V.

AU - Kharlamova, V. Yu

AU - Kokovkin, V. V.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Substitution of chloride ions in AuCl4 − with ethylenediamine (en) and propylenediamine (tn) is studied by capillary zone electrophoresis at I = 0.05 M and T = 25°C. The substitution constants are determined: AuenCl2 + + en = Auen2 3+ + 2Cl–, logK2 = 10.4; AuCl4 − + tn = AutnCl2 + + 2Cl–, logK1 = 16.1; AutnCl2 + + tn = Autn3+ 2 + 2Cl–, logK2 = 12.0.

AB - Substitution of chloride ions in AuCl4 − with ethylenediamine (en) and propylenediamine (tn) is studied by capillary zone electrophoresis at I = 0.05 M and T = 25°C. The substitution constants are determined: AuenCl2 + + en = Auen2 3+ + 2Cl–, logK2 = 10.4; AuCl4 − + tn = AutnCl2 + + 2Cl–, logK1 = 16.1; AutnCl2 + + tn = Autn3+ 2 + 2Cl–, logK2 = 12.0.

KW - PLANAR 4-CO-ORDINATE COMPLEXES

KW - STABILITY-CONSTANTS

KW - CHELATE LIGANDS

KW - METAL-COMPLEXES

KW - GOLD(III)

KW - DISPLACEMENT

KW - KINETICS

UR - http://www.scopus.com/inward/record.url?scp=85043340775&partnerID=8YFLogxK

U2 - 10.1134/S0036023618010126

DO - 10.1134/S0036023618010126

M3 - Article

AN - SCOPUS:85043340775

VL - 63

SP - 134

EP - 139

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 1

ER -

ID: 10422661