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Investigation of Chloride Ion Substitution Equilibria in AuCl 4 − with Ethylenediamine and 1,3-Diaminopropane Using Capillary Zone Electrophoresis. / Mironov, I. V.; Kharlamova, V. Yu; Kokovkin, V. V.

In: Russian Journal of Inorganic Chemistry, Vol. 63, No. 1, 01.01.2018, p. 134-139.

Research output: Contribution to journal › Article › peer-review

Harvard

Mironov, IV, Kharlamova, VY & Kokovkin, VV 2018, 'Investigation of Chloride Ion Substitution Equilibria in AuCl 4 − with Ethylenediamine and 1,3-Diaminopropane Using Capillary Zone Electrophoresis', Russian Journal of Inorganic Chemistry, vol. 63, no. 1, pp. 134-139. https://doi.org/10.1134/S0036023618010126

APA

Mironov, I. V., Kharlamova, V. Y., & Kokovkin, V. V. (2018). Investigation of Chloride Ion Substitution Equilibria in AuCl 4 − with Ethylenediamine and 1,3-Diaminopropane Using Capillary Zone Electrophoresis. Russian Journal of Inorganic Chemistry, 63(1), 134-139. https://doi.org/10.1134/S0036023618010126

Vancouver

Mironov IV, Kharlamova VY, Kokovkin VV. Investigation of Chloride Ion Substitution Equilibria in AuCl 4 − with Ethylenediamine and 1,3-Diaminopropane Using Capillary Zone Electrophoresis. Russian Journal of Inorganic Chemistry. 2018 Jan 1;63(1):134-139. doi: 10.1134/S0036023618010126

Author

Mironov, I. V. ; Kharlamova, V. Yu ; Kokovkin, V. V. / Investigation of Chloride Ion Substitution Equilibria in AuCl 4 − with Ethylenediamine and 1,3-Diaminopropane Using Capillary Zone Electrophoresis. In: Russian Journal of Inorganic Chemistry. 2018 ; Vol. 63, No. 1. pp. 134-139.

BibTeX

@article{f2cf59baaccc4330a11cbeb67b85e984,
title = "Investigation of Chloride Ion Substitution Equilibria in AuCl 4 − with Ethylenediamine and 1,3-Diaminopropane Using Capillary Zone Electrophoresis",
abstract = "Substitution of chloride ions in AuCl4 − with ethylenediamine (en) and propylenediamine (tn) is studied by capillary zone electrophoresis at I = 0.05 M and T = 25°C. The substitution constants are determined: AuenCl2 + + en = Auen2 3+ + 2Cl–, logK2 = 10.4; AuCl4 − + tn = AutnCl2 + + 2Cl–, logK1 = 16.1; AutnCl2 + + tn = Autn3+ 2 + 2Cl–, logK2 = 12.0.",
keywords = "PLANAR 4-CO-ORDINATE COMPLEXES, STABILITY-CONSTANTS, CHELATE LIGANDS, METAL-COMPLEXES, GOLD(III), DISPLACEMENT, KINETICS",
author = "Mironov, {I. V.} and Kharlamova, {V. Yu} and Kokovkin, {V. V.}",
year = "2018",
month = jan,
day = "1",
doi = "10.1134/S0036023618010126",
language = "English",
volume = "63",
pages = "134--139",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "1",

}

RIS

TY - JOUR

T1 - Investigation of Chloride Ion Substitution Equilibria in AuCl 4 − with Ethylenediamine and 1,3-Diaminopropane Using Capillary Zone Electrophoresis

AU - Mironov, I. V.

AU - Kharlamova, V. Yu

AU - Kokovkin, V. V.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Substitution of chloride ions in AuCl4 − with ethylenediamine (en) and propylenediamine (tn) is studied by capillary zone electrophoresis at I = 0.05 M and T = 25°C. The substitution constants are determined: AuenCl2 + + en = Auen2 3+ + 2Cl–, logK2 = 10.4; AuCl4 − + tn = AutnCl2 + + 2Cl–, logK1 = 16.1; AutnCl2 + + tn = Autn3+ 2 + 2Cl–, logK2 = 12.0.

AB - Substitution of chloride ions in AuCl4 − with ethylenediamine (en) and propylenediamine (tn) is studied by capillary zone electrophoresis at I = 0.05 M and T = 25°C. The substitution constants are determined: AuenCl2 + + en = Auen2 3+ + 2Cl–, logK2 = 10.4; AuCl4 − + tn = AutnCl2 + + 2Cl–, logK1 = 16.1; AutnCl2 + + tn = Autn3+ 2 + 2Cl–, logK2 = 12.0.

KW - PLANAR 4-CO-ORDINATE COMPLEXES

KW - STABILITY-CONSTANTS

KW - CHELATE LIGANDS

KW - METAL-COMPLEXES

KW - GOLD(III)

KW - DISPLACEMENT

KW - KINETICS

UR - http://www.scopus.com/inward/record.url?scp=85043340775&partnerID=8YFLogxK

U2 - 10.1134/S0036023618010126

DO - 10.1134/S0036023618010126

M3 - Article

AN - SCOPUS:85043340775

VL - 63

SP - 134

EP - 139

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 1

ER -

ID: 10422661