Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
HPHT growth and characterization of diamond from a copper-carbon system. / Kupriyanov, Igor N.; Khokhryakov, Alexander F.; Borzdov, Yuri M. и др.
в: Diamond and Related Materials, Том 69, 01.10.2016, стр. 198-206.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - HPHT growth and characterization of diamond from a copper-carbon system
AU - Kupriyanov, Igor N.
AU - Khokhryakov, Alexander F.
AU - Borzdov, Yuri M.
AU - Palyanov, Yuri N.
PY - 2016/10/1
Y1 - 2016/10/1
N2 - Diamond crystallization in the Cu-C system is studied at high pressure high temperature conditions of 7.0 GPa and 1500–1800 °C. The minimum temperature of diamond synthesis by spontaneous nucleation is found to be 1800 °C. Diamond layers of optical quality are grown on the seed crystals via the chemical-potential difference method. From the infrared absorption measurements it is found that the diamond layers grown on the (100) faces of the seed crystals contain nitrogen impurities in the form of A centers with concentration from 700 to 1100 ppm and show strong hydrogen-related absorption peak at 3107 cm− 1. A number of specific optical centers are found in photoluminescence spectra recorded for diamond layers grown on both (100) and (111) faces of the seed crystals. The newly observed 1.748 eV center is tentatively assigned to defects involving Cu impurities. The 1.787 eV center is suggested to appear preferentially in diamonds with high contents of nitrogen and hydrogen impurities.
AB - Diamond crystallization in the Cu-C system is studied at high pressure high temperature conditions of 7.0 GPa and 1500–1800 °C. The minimum temperature of diamond synthesis by spontaneous nucleation is found to be 1800 °C. Diamond layers of optical quality are grown on the seed crystals via the chemical-potential difference method. From the infrared absorption measurements it is found that the diamond layers grown on the (100) faces of the seed crystals contain nitrogen impurities in the form of A centers with concentration from 700 to 1100 ppm and show strong hydrogen-related absorption peak at 3107 cm− 1. A number of specific optical centers are found in photoluminescence spectra recorded for diamond layers grown on both (100) and (111) faces of the seed crystals. The newly observed 1.748 eV center is tentatively assigned to defects involving Cu impurities. The 1.787 eV center is suggested to appear preferentially in diamonds with high contents of nitrogen and hydrogen impurities.
KW - Defect characterization
KW - High pressure high temperature (HPHT)
KW - Impurities
KW - Optical properties
KW - Solvent-catalysts
KW - Synthetic diamond
UR - http://www.scopus.com/inward/record.url?scp=84987973396&partnerID=8YFLogxK
U2 - 10.1016/j.diamond.2016.09.009
DO - 10.1016/j.diamond.2016.09.009
M3 - Article
AN - SCOPUS:84987973396
VL - 69
SP - 198
EP - 206
JO - Diamond and Related Materials
JF - Diamond and Related Materials
SN - 0925-9635
ER -
ID: 25724455