Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Gas-Phase Carbonylation of Dimethoxymethane to Methyl Methoxyacetate on Solid Acids : The Effect of Acidity on the Catalytic Activity. / Badmaev, S. D.; Smorygina, A. S.; Paukshtis, E. A. и др.
в: Kinetics and Catalysis, Том 59, № 1, 01.01.2018, стр. 99-103.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Gas-Phase Carbonylation of Dimethoxymethane to Methyl Methoxyacetate on Solid Acids
T2 - The Effect of Acidity on the Catalytic Activity
AU - Badmaev, S. D.
AU - Smorygina, A. S.
AU - Paukshtis, E. A.
AU - Belyaev, V. D.
AU - Sobyanin, V. A.
AU - Parmon, V. N.
N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.
PY - 2018/1/1
Y1 - 2018/1/1
N2 - The gas-phase carbonylation reaction of dimethoxymethane (DMM) to methyl methoxyacetate on different solid acids was studied. It was established that this reaction was accompanied by the occurrence of a side reaction of DMM disproportionation into dimethyl ether and methyl formate. It was shown that the activity of solid acids in both of the reactions depends on the strength of Brønsted acid sites according to an equation like the Brønsted–Evans–Polanyi–Semenov correlations.
AB - The gas-phase carbonylation reaction of dimethoxymethane (DMM) to methyl methoxyacetate on different solid acids was studied. It was established that this reaction was accompanied by the occurrence of a side reaction of DMM disproportionation into dimethyl ether and methyl formate. It was shown that the activity of solid acids in both of the reactions depends on the strength of Brønsted acid sites according to an equation like the Brønsted–Evans–Polanyi–Semenov correlations.
KW - Brønsted–Evans–Polanyi–Semenov correlations
KW - carbonylation
KW - dimethoxymethane
KW - dimethyl ether
KW - disproportionation
KW - methyl formate
KW - methyl methoxyacetate
KW - methylal
KW - solid acids
KW - OXIDATION
KW - DIMETHYL ETHER
KW - Bronsted-Evans-Polanyi-Semenov correlations
UR - http://www.scopus.com/inward/record.url?scp=85043296264&partnerID=8YFLogxK
U2 - 10.1134/S0023158418010020
DO - 10.1134/S0023158418010020
M3 - Article
AN - SCOPUS:85043296264
VL - 59
SP - 99
EP - 103
JO - Kinetics and Catalysis
JF - Kinetics and Catalysis
SN - 0023-1584
IS - 1
ER -
ID: 10354145