Gas-Phase Carbonylation of Dimethoxymethane to Methyl Methoxyacetate on Solid Acids

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Gas-Phase Carbonylation of Dimethoxymethane to Methyl Methoxyacetate on Solid Acids : The Effect of Acidity on the Catalytic Activity. / Badmaev, S. D.; Smorygina, A. S.; Paukshtis, E. A. et al.

In: Kinetics and Catalysis, Vol. 59, No. 1, 01.01.2018, p. 99-103.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{8643aa5e481f428ba97f99efca846e04,

title = "Gas-Phase Carbonylation of Dimethoxymethane to Methyl Methoxyacetate on Solid Acids: The Effect of Acidity on the Catalytic Activity",

abstract = "The gas-phase carbonylation reaction of dimethoxymethane (DMM) to methyl methoxyacetate on different solid acids was studied. It was established that this reaction was accompanied by the occurrence of a side reaction of DMM disproportionation into dimethyl ether and methyl formate. It was shown that the activity of solid acids in both of the reactions depends on the strength of Br{\o}nsted acid sites according to an equation like the Br{\o}nsted–Evans–Polanyi–Semenov correlations.",

keywords = "Br{\o}nsted–Evans–Polanyi–Semenov correlations, carbonylation, dimethoxymethane, dimethyl ether, disproportionation, methyl formate, methyl methoxyacetate, methylal, solid acids, OXIDATION, DIMETHYL ETHER, Bronsted-Evans-Polanyi-Semenov correlations",

author = "Badmaev, {S. D.} and Smorygina, {A. S.} and Paukshtis, {E. A.} and Belyaev, {V. D.} and Sobyanin, {V. A.} and Parmon, {V. N.}",

note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",

year = "2018",

month = jan,

day = "1",

doi = "10.1134/S0023158418010020",

language = "English",

volume = "59",

pages = "99--103",

journal = "Kinetics and Catalysis",

issn = "0023-1584",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "1",

}

RIS

TY - JOUR

T1 - Gas-Phase Carbonylation of Dimethoxymethane to Methyl Methoxyacetate on Solid Acids

T2 - The Effect of Acidity on the Catalytic Activity

AU - Badmaev, S. D.

AU - Smorygina, A. S.

AU - Paukshtis, E. A.

AU - Belyaev, V. D.

AU - Sobyanin, V. A.

AU - Parmon, V. N.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - The gas-phase carbonylation reaction of dimethoxymethane (DMM) to methyl methoxyacetate on different solid acids was studied. It was established that this reaction was accompanied by the occurrence of a side reaction of DMM disproportionation into dimethyl ether and methyl formate. It was shown that the activity of solid acids in both of the reactions depends on the strength of Brønsted acid sites according to an equation like the Brønsted–Evans–Polanyi–Semenov correlations.

AB - The gas-phase carbonylation reaction of dimethoxymethane (DMM) to methyl methoxyacetate on different solid acids was studied. It was established that this reaction was accompanied by the occurrence of a side reaction of DMM disproportionation into dimethyl ether and methyl formate. It was shown that the activity of solid acids in both of the reactions depends on the strength of Brønsted acid sites according to an equation like the Brønsted–Evans–Polanyi–Semenov correlations.

KW - Brønsted–Evans–Polanyi–Semenov correlations

KW - carbonylation

KW - dimethoxymethane

KW - dimethyl ether

KW - disproportionation

KW - methyl formate

KW - methyl methoxyacetate

KW - methylal

KW - solid acids

KW - OXIDATION

KW - DIMETHYL ETHER

KW - Bronsted-Evans-Polanyi-Semenov correlations

UR - http://www.scopus.com/inward/record.url?scp=85043296264&partnerID=8YFLogxK

U2 - 10.1134/S0023158418010020

DO - 10.1134/S0023158418010020

M3 - Article

AN - SCOPUS:85043296264

VL - 59

SP - 99

EP - 103

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

SN - 0023-1584

IS - 1

ER -

ID: 10354145

Gas-Phase Carbonylation of Dimethoxymethane to Methyl Methoxyacetate on Solid Acids: The Effect of Acidity on the Catalytic Activity

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