Результаты исследований: Научные публикации в периодических изданиях › обзорная статья › Рецензирование
Femtochemistry methods for studying the photophysics and photochemistry of halide complexes of platinum metals. / Glebov, E. M.
в: Russian Chemical Bulletin, Том 71, № 5, 05.2022, стр. 858-877.Результаты исследований: Научные публикации в периодических изданиях › обзорная статья › Рецензирование
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TY - JOUR
T1 - Femtochemistry methods for studying the photophysics and photochemistry of halide complexes of platinum metals
AU - Glebov, E. M.
N1 - Funding Information: This work was financially supported by the Russian Science Foundation (Project No. 22-33-00248). Publisher Copyright: © 2022, Springer Science+Business Media LLC.
PY - 2022/5
Y1 - 2022/5
N2 - The primary (ultrafast) photophysical and photochemical processes characteristic of the following halogen-containing complexes of platinum group metals were examined: hexahalide complexes (PtIVBr62−, PtIVCl62−, IrIVCl62−, IrIVBr62−, OsIVCl62−, and OsIVBr62−), pseudohexahalide complex PtIV(SCN)62−, and mixed diiodide complexes of PtIV. The historical and practical aspects of the photochemistry of platinum metals complexes are presented. The ultrafast (femtosecond) research methods and general features of ultrafast processes that occur in the presence of coordination compounds are outlined. The stages of target product transformation from the absorption of a light quantum to the formation of final products are considered. The levels of completeness of research for each of the systems examined are listed.
AB - The primary (ultrafast) photophysical and photochemical processes characteristic of the following halogen-containing complexes of platinum group metals were examined: hexahalide complexes (PtIVBr62−, PtIVCl62−, IrIVCl62−, IrIVBr62−, OsIVCl62−, and OsIVBr62−), pseudohexahalide complex PtIV(SCN)62−, and mixed diiodide complexes of PtIV. The historical and practical aspects of the photochemistry of platinum metals complexes are presented. The ultrafast (femtosecond) research methods and general features of ultrafast processes that occur in the presence of coordination compounds are outlined. The stages of target product transformation from the absorption of a light quantum to the formation of final products are considered. The levels of completeness of research for each of the systems examined are listed.
KW - chain photochemical reactions
KW - electronic excited states
KW - halide complexes of platinum group metals
KW - iridium
KW - osmium
KW - photochemistry
KW - photophysics
KW - platinum
KW - primary photochemical processes
KW - short-lived intermediates
KW - ultrafast fluorescence
KW - ultrafast spectroscopy
UR - http://www.scopus.com/inward/record.url?scp=85130410359&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/91660bf3-79f3-3a30-8feb-57bc98baa9e5/
U2 - 10.1007/s11172-022-3486-2
DO - 10.1007/s11172-022-3486-2
M3 - Review article
AN - SCOPUS:85130410359
VL - 71
SP - 858
EP - 877
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 5
ER -
ID: 36169515