Femtochemistry methods for studying the photophysics and photochemistry of halide complexes of platinum metals

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Femtochemistry methods for studying the photophysics and photochemistry of halide complexes of platinum metals. / Glebov, E. M.

In: Russian Chemical Bulletin, Vol. 71, No. 5, 05.2022, p. 858-877.

Research output: Contribution to journal › Review article › peer-review

BibTeX

@article{a7c667ff9ccf4469b1ff75d602b571d7,

title = "Femtochemistry methods for studying the photophysics and photochemistry of halide complexes of platinum metals",

abstract = "The primary (ultrafast) photophysical and photochemical processes characteristic of the following halogen-containing complexes of platinum group metals were examined: hexahalide complexes (PtIVBr62−, PtIVCl62−, IrIVCl62−, IrIVBr62−, OsIVCl62−, and OsIVBr62−), pseudohexahalide complex PtIV(SCN)62−, and mixed diiodide complexes of PtIV. The historical and practical aspects of the photochemistry of platinum metals complexes are presented. The ultrafast (femtosecond) research methods and general features of ultrafast processes that occur in the presence of coordination compounds are outlined. The stages of target product transformation from the absorption of a light quantum to the formation of final products are considered. The levels of completeness of research for each of the systems examined are listed.",

keywords = "chain photochemical reactions, electronic excited states, halide complexes of platinum group metals, iridium, osmium, photochemistry, photophysics, platinum, primary photochemical processes, short-lived intermediates, ultrafast fluorescence, ultrafast spectroscopy",

author = "Glebov, {E. M.}",

note = "Funding Information: This work was financially supported by the Russian Science Foundation (Project No. 22-33-00248). Publisher Copyright: {\textcopyright} 2022, Springer Science+Business Media LLC.",

year = "2022",

month = may,

doi = "10.1007/s11172-022-3486-2",

language = "English",

volume = "71",

pages = "858--877",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer Nature",

number = "5",

}

RIS

TY - JOUR

T1 - Femtochemistry methods for studying the photophysics and photochemistry of halide complexes of platinum metals

AU - Glebov, E. M.

PY - 2022/5

Y1 - 2022/5

N2 - The primary (ultrafast) photophysical and photochemical processes characteristic of the following halogen-containing complexes of platinum group metals were examined: hexahalide complexes (PtIVBr62−, PtIVCl62−, IrIVCl62−, IrIVBr62−, OsIVCl62−, and OsIVBr62−), pseudohexahalide complex PtIV(SCN)62−, and mixed diiodide complexes of PtIV. The historical and practical aspects of the photochemistry of platinum metals complexes are presented. The ultrafast (femtosecond) research methods and general features of ultrafast processes that occur in the presence of coordination compounds are outlined. The stages of target product transformation from the absorption of a light quantum to the formation of final products are considered. The levels of completeness of research for each of the systems examined are listed.

AB - The primary (ultrafast) photophysical and photochemical processes characteristic of the following halogen-containing complexes of platinum group metals were examined: hexahalide complexes (PtIVBr62−, PtIVCl62−, IrIVCl62−, IrIVBr62−, OsIVCl62−, and OsIVBr62−), pseudohexahalide complex PtIV(SCN)62−, and mixed diiodide complexes of PtIV. The historical and practical aspects of the photochemistry of platinum metals complexes are presented. The ultrafast (femtosecond) research methods and general features of ultrafast processes that occur in the presence of coordination compounds are outlined. The stages of target product transformation from the absorption of a light quantum to the formation of final products are considered. The levels of completeness of research for each of the systems examined are listed.

KW - chain photochemical reactions

KW - electronic excited states

KW - halide complexes of platinum group metals

KW - iridium

KW - osmium

KW - photochemistry

KW - photophysics

KW - platinum

KW - primary photochemical processes

KW - short-lived intermediates

KW - ultrafast fluorescence

KW - ultrafast spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=85130410359&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/91660bf3-79f3-3a30-8feb-57bc98baa9e5/

U2 - 10.1007/s11172-022-3486-2

DO - 10.1007/s11172-022-3486-2

M3 - Review article

AN - SCOPUS:85130410359

VL - 71

SP - 858

EP - 877

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 5

ER -

ID: 36169515