Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions. / Genaev, Alexander M.; Salnikov, George E.; Shernyukov, Andrey V. и др.
в: Mendeleev Communications, Том 28, № 1, 01.01.2018, стр. 27-28.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions
AU - Genaev, Alexander M.
AU - Salnikov, George E.
AU - Shernyukov, Andrey V.
AU - Zhu, Zhongwei
AU - Koltunov, Konstantin Yu
PY - 2018/1/1
Y1 - 2018/1/1
N2 - Compared with the parent 1,1’-bi-2-naphthol (BINOL), its dimethyl ether is highly resistant towards racemization under moderate acidic conditions. This finding confirms the hypothetical mechanism of BINOL atropisomerization including internal rotation around the C1 sp3 –C1' sp3 bond in its protonatedforms.
AB - Compared with the parent 1,1’-bi-2-naphthol (BINOL), its dimethyl ether is highly resistant towards racemization under moderate acidic conditions. This finding confirms the hypothetical mechanism of BINOL atropisomerization including internal rotation around the C1 sp3 –C1' sp3 bond in its protonatedforms.
KW - CATALYSIS
KW - 1,1'-BI-2-NAPHTHOL
UR - http://www.scopus.com/inward/record.url?scp=85041595732&partnerID=8YFLogxK
U2 - 10.1016/j.mencom.2018.01.007
DO - 10.1016/j.mencom.2018.01.007
M3 - Article
AN - SCOPUS:85041595732
VL - 28
SP - 27
EP - 28
JO - Mendeleev Communications
JF - Mendeleev Communications
SN - 0959-9436
IS - 1
ER -
ID: 10352413