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Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions. / Genaev, Alexander M.; Salnikov, George E.; Shernyukov, Andrey V. et al.

In: Mendeleev Communications, Vol. 28, No. 1, 01.01.2018, p. 27-28.

Research output: Contribution to journal › Article › peer-review

Harvard

Genaev, AM, Salnikov, GE, Shernyukov, AV, Zhu, Z & Koltunov, KY 2018, 'Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions', Mendeleev Communications, vol. 28, no. 1, pp. 27-28. https://doi.org/10.1016/j.mencom.2018.01.007

APA

Genaev, A. M., Salnikov, G. E., Shernyukov, A. V., Zhu, Z., & Koltunov, K. Y. (2018). Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions. Mendeleev Communications, 28(1), 27-28. https://doi.org/10.1016/j.mencom.2018.01.007

Vancouver

Genaev AM, Salnikov GE, Shernyukov AV, Zhu Z, Koltunov KY. Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions. Mendeleev Communications. 2018 Jan 1;28(1):27-28. doi: 10.1016/j.mencom.2018.01.007

Author

Genaev, Alexander M. ; Salnikov, George E. ; Shernyukov, Andrey V. et al. / Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions. In: Mendeleev Communications. 2018 ; Vol. 28, No. 1. pp. 27-28.

BibTeX

@article{c5bd8e8b6700442a89aa2a41bf230ea8,
title = "Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions",
abstract = "Compared with the parent 1,1{\textquoteright}-bi-2-naphthol (BINOL), its dimethyl ether is highly resistant towards racemization under moderate acidic conditions. This finding confirms the hypothetical mechanism of BINOL atropisomerization including internal rotation around the C1 sp3 –C1' sp3 bond in its protonatedforms.",
keywords = "CATALYSIS, 1,1'-BI-2-NAPHTHOL",
author = "Genaev, {Alexander M.} and Salnikov, {George E.} and Shernyukov, {Andrey V.} and Zhongwei Zhu and Koltunov, {Konstantin Yu}",
year = "2018",
month = jan,
day = "1",
doi = "10.1016/j.mencom.2018.01.007",
language = "English",
volume = "28",
pages = "27--28",
journal = "Mendeleev Communications",
issn = "0959-9436",
publisher = "Elsevier",
number = "1",

}

RIS

TY - JOUR

T1 - Enhanced enantiostability of BINOL dimethyl ether under moderate acidic conditions

AU - Genaev, Alexander M.

AU - Salnikov, George E.

AU - Shernyukov, Andrey V.

AU - Zhu, Zhongwei

AU - Koltunov, Konstantin Yu

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Compared with the parent 1,1’-bi-2-naphthol (BINOL), its dimethyl ether is highly resistant towards racemization under moderate acidic conditions. This finding confirms the hypothetical mechanism of BINOL atropisomerization including internal rotation around the C1 sp3 –C1' sp3 bond in its protonatedforms.

AB - Compared with the parent 1,1’-bi-2-naphthol (BINOL), its dimethyl ether is highly resistant towards racemization under moderate acidic conditions. This finding confirms the hypothetical mechanism of BINOL atropisomerization including internal rotation around the C1 sp3 –C1' sp3 bond in its protonatedforms.

KW - CATALYSIS

KW - 1,1'-BI-2-NAPHTHOL

UR - http://www.scopus.com/inward/record.url?scp=85041595732&partnerID=8YFLogxK

U2 - 10.1016/j.mencom.2018.01.007

DO - 10.1016/j.mencom.2018.01.007

M3 - Article

AN - SCOPUS:85041595732

VL - 28

SP - 27

EP - 28

JO - Mendeleev Communications

JF - Mendeleev Communications

SN - 0959-9436

IS - 1

ER -

ID: 10352413