TY - JOUR

T1 - Electron–Nuclear Alignment in Radicals Formed by Photochemical Decomposition of Molecules

AU - Purtov, P. A.

N1 - This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained. Публикация для корректировки.

PY - 2023/12

Y1 - 2023/12

N2 - Calculations of electron–nuclear alignment (CIDEP multiplet effect) in radicals formed as a result of the photochemical decomposition of molecules have been performed. There is a mutual ordering of spins in the radicals: the electron and nuclear spins in the radical are oriented parallel or antiparallel. The populations of stationary states of radicals in weak magnetic fields have been calculated in the framework of the kinematic approach.

AB - Calculations of electron–nuclear alignment (CIDEP multiplet effect) in radicals formed as a result of the photochemical decomposition of molecules have been performed. There is a mutual ordering of spins in the radicals: the electron and nuclear spins in the radical are oriented parallel or antiparallel. The populations of stationary states of radicals in weak magnetic fields have been calculated in the framework of the kinematic approach.

KW - Zeeman interaction

KW - density matrix

KW - hyperfine interaction

KW - photochemical decomposition

KW - radical pair

KW - spin alignment

KW - spin polarization

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85185948003&origin=inward&txGid=287a091fb9d3f43002a5fb7ffc2c614f

UR - https://www.mendeley.com/catalogue/ac2a0c3b-4dc0-30d5-8451-7524b7d20552/

U2 - 10.1134/S001814392309014X

DO - 10.1134/S001814392309014X

M3 - Article

VL - 57

SP - S460-S463

JO - High Energy Chemistry

JF - High Energy Chemistry

SN - 0018-1439

IS - Suppl 3

ER -