Research output: Contribution to journal › Article › peer-review
Electron–Nuclear Alignment in Radicals Formed by Photochemical Decomposition of Molecules. / Purtov, P. A.
In: High Energy Chemistry, Vol. 57, No. Suppl 3, 12.2023, p. S460-S463.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Electron–Nuclear Alignment in Radicals Formed by Photochemical Decomposition of Molecules
AU - Purtov, P. A.
N1 - This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained. Публикация для корректировки.
PY - 2023/12
Y1 - 2023/12
N2 - Calculations of electron–nuclear alignment (CIDEP multiplet effect) in radicals formed as a result of the photochemical decomposition of molecules have been performed. There is a mutual ordering of spins in the radicals: the electron and nuclear spins in the radical are oriented parallel or antiparallel. The populations of stationary states of radicals in weak magnetic fields have been calculated in the framework of the kinematic approach.
AB - Calculations of electron–nuclear alignment (CIDEP multiplet effect) in radicals formed as a result of the photochemical decomposition of molecules have been performed. There is a mutual ordering of spins in the radicals: the electron and nuclear spins in the radical are oriented parallel or antiparallel. The populations of stationary states of radicals in weak magnetic fields have been calculated in the framework of the kinematic approach.
KW - Zeeman interaction
KW - density matrix
KW - hyperfine interaction
KW - photochemical decomposition
KW - radical pair
KW - spin alignment
KW - spin polarization
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85185948003&origin=inward&txGid=287a091fb9d3f43002a5fb7ffc2c614f
UR - https://www.mendeley.com/catalogue/ac2a0c3b-4dc0-30d5-8451-7524b7d20552/
U2 - 10.1134/S001814392309014X
DO - 10.1134/S001814392309014X
M3 - Article
VL - 57
SP - S460-S463
JO - High Energy Chemistry
JF - High Energy Chemistry
SN - 0018-1439
IS - Suppl 3
ER -
ID: 59727779