Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Effect of temperature and pressure on mixed oxide solid solutions. / Petrushina, M. Yu; Dedova, E. S.; Yusenko, K. V. и др.
в: Inorganic Chemistry Communications, Том 117, 107965, 07.2020.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Effect of temperature and pressure on mixed oxide solid solutions
AU - Petrushina, M. Yu
AU - Dedova, E. S.
AU - Yusenko, K. V.
AU - Portnyagin, A. S.
AU - Papynov, E. K.
AU - Filatov, E. Yu
AU - Korenev, S. V.
AU - Gubanov, A. I.
N1 - Publisher Copyright: © 2020 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/7
Y1 - 2020/7
N2 - A hydrothermal synthesis of ZrW2-xMoxO8 (0 ≤ x ≤ 2) from the corresponding precursors is reported in this paper. High-temperature and high-pressure data are presented for the sample with x = 1.6. An increase in temperature initiates the phase transition from tetragonal precursor to orthorhombic-ZrW2-xMoxO8 (x = 1.6) with the subsequent formation of cubic and trigonal phases. The thermolysis parameter of the disordered cubic ZrW2-xMoxO8 (x = 1.6) phase is 803 K, and the coefficient of thermal expansion is α = -4.6∙10–6 K−1. Data on ZrW2-xMoxO8 (x = 1.6) structure as a function of pressure are obtained for the first time. Pressure-induced changes from cubic to orthorhombic ZrW2-xMoxO8 (x = 1.6) phase at 1.38 GPa are observed. The sample amorphization is irreversible during decompression.
AB - A hydrothermal synthesis of ZrW2-xMoxO8 (0 ≤ x ≤ 2) from the corresponding precursors is reported in this paper. High-temperature and high-pressure data are presented for the sample with x = 1.6. An increase in temperature initiates the phase transition from tetragonal precursor to orthorhombic-ZrW2-xMoxO8 (x = 1.6) with the subsequent formation of cubic and trigonal phases. The thermolysis parameter of the disordered cubic ZrW2-xMoxO8 (x = 1.6) phase is 803 K, and the coefficient of thermal expansion is α = -4.6∙10–6 K−1. Data on ZrW2-xMoxO8 (x = 1.6) structure as a function of pressure are obtained for the first time. Pressure-induced changes from cubic to orthorhombic ZrW2-xMoxO8 (x = 1.6) phase at 1.38 GPa are observed. The sample amorphization is irreversible during decompression.
KW - NEGATIVE THERMAL-EXPANSION
KW - ZRW2O8
KW - COMPRESSIBILITY
KW - TRANSITIONS
UR - http://www.scopus.com/inward/record.url?scp=85084819664&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2020.107965
DO - 10.1016/j.inoche.2020.107965
M3 - Article
AN - SCOPUS:85084819664
VL - 117
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
M1 - 107965
ER -
ID: 24312500