Effect of temperature and pressure on mixed oxide solid solutions

Standard

Effect of temperature and pressure on mixed oxide solid solutions. / Petrushina, M. Yu; Dedova, E. S.; Yusenko, K. V. et al.

In: Inorganic Chemistry Communications, Vol. 117, 107965, 07.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrushina, MY, Dedova, ES, Yusenko, KV, Portnyagin, AS, Papynov, EK, Filatov, EY , Korenev, SV & Gubanov, AI 2020, 'Effect of temperature and pressure on mixed oxide solid solutions', Inorganic Chemistry Communications, vol. 117, 107965. https://doi.org/10.1016/j.inoche.2020.107965

APA

Petrushina, M. Y., Dedova, E. S., Yusenko, K. V., Portnyagin, A. S., Papynov, E. K., Filatov, E. Y., Korenev, S. V., & Gubanov, A. I. (2020). Effect of temperature and pressure on mixed oxide solid solutions. Inorganic Chemistry Communications, 117, [107965]. https://doi.org/10.1016/j.inoche.2020.107965

Vancouver

Petrushina MY, Dedova ES, Yusenko KV, Portnyagin AS, Papynov EK, Filatov EY et al. Effect of temperature and pressure on mixed oxide solid solutions. Inorganic Chemistry Communications. 2020 Jul;117:107965. doi: 10.1016/j.inoche.2020.107965

Author

Petrushina, M. Yu ; Dedova, E. S. ; Yusenko, K. V. et al. / Effect of temperature and pressure on mixed oxide solid solutions. In: Inorganic Chemistry Communications. 2020 ; Vol. 117.

BibTeX

@article{689d26ebaf0b4c15a5ee3964870f8ba2,

title = "Effect of temperature and pressure on mixed oxide solid solutions",

abstract = "A hydrothermal synthesis of ZrW2-xMoxO8 (0 ≤ x ≤ 2) from the corresponding precursors is reported in this paper. High-temperature and high-pressure data are presented for the sample with x = 1.6. An increase in temperature initiates the phase transition from tetragonal precursor to orthorhombic-ZrW2-xMoxO8 (x = 1.6) with the subsequent formation of cubic and trigonal phases. The thermolysis parameter of the disordered cubic ZrW2-xMoxO8 (x = 1.6) phase is 803 K, and the coefficient of thermal expansion is α = -4.6∙10–6 K−1. Data on ZrW2-xMoxO8 (x = 1.6) structure as a function of pressure are obtained for the first time. Pressure-induced changes from cubic to orthorhombic ZrW2-xMoxO8 (x = 1.6) phase at 1.38 GPa are observed. The sample amorphization is irreversible during decompression.",

keywords = "NEGATIVE THERMAL-EXPANSION, ZRW2O8, COMPRESSIBILITY, TRANSITIONS",

author = "Petrushina, {M. Yu} and Dedova, {E. S.} and Yusenko, {K. V.} and Portnyagin, {A. S.} and Papynov, {E. K.} and Filatov, {E. Yu} and Korenev, {S. V.} and Gubanov, {A. I.}",

year = "2020",

month = jul,

doi = "10.1016/j.inoche.2020.107965",

language = "English",

volume = "117",

journal = "Inorganic Chemistry Communication",

issn = "1387-7003",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Effect of temperature and pressure on mixed oxide solid solutions

AU - Petrushina, M. Yu

AU - Dedova, E. S.

AU - Yusenko, K. V.

AU - Portnyagin, A. S.

AU - Papynov, E. K.

AU - Filatov, E. Yu

AU - Korenev, S. V.

AU - Gubanov, A. I.

PY - 2020/7

Y1 - 2020/7

N2 - A hydrothermal synthesis of ZrW2-xMoxO8 (0 ≤ x ≤ 2) from the corresponding precursors is reported in this paper. High-temperature and high-pressure data are presented for the sample with x = 1.6. An increase in temperature initiates the phase transition from tetragonal precursor to orthorhombic-ZrW2-xMoxO8 (x = 1.6) with the subsequent formation of cubic and trigonal phases. The thermolysis parameter of the disordered cubic ZrW2-xMoxO8 (x = 1.6) phase is 803 K, and the coefficient of thermal expansion is α = -4.6∙10–6 K−1. Data on ZrW2-xMoxO8 (x = 1.6) structure as a function of pressure are obtained for the first time. Pressure-induced changes from cubic to orthorhombic ZrW2-xMoxO8 (x = 1.6) phase at 1.38 GPa are observed. The sample amorphization is irreversible during decompression.

AB - A hydrothermal synthesis of ZrW2-xMoxO8 (0 ≤ x ≤ 2) from the corresponding precursors is reported in this paper. High-temperature and high-pressure data are presented for the sample with x = 1.6. An increase in temperature initiates the phase transition from tetragonal precursor to orthorhombic-ZrW2-xMoxO8 (x = 1.6) with the subsequent formation of cubic and trigonal phases. The thermolysis parameter of the disordered cubic ZrW2-xMoxO8 (x = 1.6) phase is 803 K, and the coefficient of thermal expansion is α = -4.6∙10–6 K−1. Data on ZrW2-xMoxO8 (x = 1.6) structure as a function of pressure are obtained for the first time. Pressure-induced changes from cubic to orthorhombic ZrW2-xMoxO8 (x = 1.6) phase at 1.38 GPa are observed. The sample amorphization is irreversible during decompression.

KW - NEGATIVE THERMAL-EXPANSION

KW - ZRW2O8

KW - COMPRESSIBILITY

KW - TRANSITIONS

UR - http://www.scopus.com/inward/record.url?scp=85084819664&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2020.107965

DO - 10.1016/j.inoche.2020.107965

M3 - Article

AN - SCOPUS:85084819664

VL - 117

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

M1 - 107965

ER -

ID: 24312500