Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Double yttrium thiosilicates AYSiS4 (A = Rb, Cs): synthesis, structure, optical properties. / Tarasenko, M. S.; Duritsyn, R. V.; Potapov, D. A. и др.
в: Journal of Structural Chemistry, Том 63, № 12, 01.12.2022, стр. 1988-1996.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Double yttrium thiosilicates AYSiS4 (A = Rb, Cs): synthesis, structure, optical properties
AU - Tarasenko, M. S.
AU - Duritsyn, R. V.
AU - Potapov, D. A.
AU - Kuratieva, N. V.
AU - Ryadun, A. A.
AU - Naumov, N. G.
N1 - FUNDING: The work was supported by the Ministry of Science and Higher Education of the Russian Federation (projects Nos. 121031700315-2 and 121031700313-8).
PY - 2022/12/1
Y1 - 2022/12/1
N2 - By the high-temperature synthesis new double yttrium thiosilicates AYSiS4, A = Rb, Cs are obtained. The compounds crystallize in the orthorhombic system (space group P212121) with the following parameters: a = 6.3381(4) Å, b = 6.5961(4) Å, c = 16.8868(12) Å for RbYSiS4 and a = 6.3303(4) Å, b = 6.6593(5) Å, c = 17.5795(13) Å for CsYSiS4. The compound with rubidium is rapidly hydrolyzed by water; the compound with cesium is stable in dry air. For CsYSiS4 the band gap estimated by diffuse reflectance is 3.8 eV. The photoluminescence spectrum has a broad band in the visible region with the maximum at λ = 492 nm (green region). The lifetimes are τ1 = 5.25 µs and τ2 = 0.26 µs with the quantum yield of
AB - By the high-temperature synthesis new double yttrium thiosilicates AYSiS4, A = Rb, Cs are obtained. The compounds crystallize in the orthorhombic system (space group P212121) with the following parameters: a = 6.3381(4) Å, b = 6.5961(4) Å, c = 16.8868(12) Å for RbYSiS4 and a = 6.3303(4) Å, b = 6.6593(5) Å, c = 17.5795(13) Å for CsYSiS4. The compound with rubidium is rapidly hydrolyzed by water; the compound with cesium is stable in dry air. For CsYSiS4 the band gap estimated by diffuse reflectance is 3.8 eV. The photoluminescence spectrum has a broad band in the visible region with the maximum at λ = 492 nm (green region). The lifetimes are τ1 = 5.25 µs and τ2 = 0.26 µs with the quantum yield of
KW - crystal structure
KW - photoluminescence
KW - thiosilicate
KW - yttrium
UR - https://www.scopus.com/inward/record.url?eid=2-s2.0-85145360604&partnerID=40&md5=81473ad72098fea498dcafcd9b3fe9b0
UR - https://www.mendeley.com/catalogue/b29a8f28-28e7-3ebf-8935-9c5a6194a09c/
U2 - 10.1134/S0022476622120101
DO - 10.1134/S0022476622120101
M3 - Article
VL - 63
SP - 1988
EP - 1996
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 12
ER -
ID: 44625920