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Double yttrium thiosilicates AYSiS4 (A = Rb, Cs): synthesis, structure, optical properties. / Tarasenko, M. S.; Duritsyn, R. V.; Potapov, D. A. et al.

In: Journal of Structural Chemistry, Vol. 63, No. 12, 01.12.2022, p. 1988-1996.

Research output: Contribution to journal › Article › peer-review

Harvard

Tarasenko, MS, Duritsyn, RV, Potapov, DA, Kuratieva, NV, Ryadun, AA & Naumov, NG 2022, 'Double yttrium thiosilicates AYSiS4 (A = Rb, Cs): synthesis, structure, optical properties', Journal of Structural Chemistry, vol. 63, no. 12, pp. 1988-1996. https://doi.org/10.1134/S0022476622120101

APA

Tarasenko, M. S., Duritsyn, R. V., Potapov, D. A., Kuratieva, N. V., Ryadun, A. A., & Naumov, N. G. (2022). Double yttrium thiosilicates AYSiS4 (A = Rb, Cs): synthesis, structure, optical properties. Journal of Structural Chemistry, 63(12), 1988-1996. https://doi.org/10.1134/S0022476622120101

Vancouver

Tarasenko MS, Duritsyn RV, Potapov DA, Kuratieva NV, Ryadun AA, Naumov NG. Double yttrium thiosilicates AYSiS4 (A = Rb, Cs): synthesis, structure, optical properties. Journal of Structural Chemistry. 2022 Dec 1;63(12):1988-1996. doi: 10.1134/S0022476622120101

Author

Tarasenko, M. S. ; Duritsyn, R. V. ; Potapov, D. A. et al. / Double yttrium thiosilicates AYSiS4 (A = Rb, Cs): synthesis, structure, optical properties. In: Journal of Structural Chemistry. 2022 ; Vol. 63, No. 12. pp. 1988-1996.

BibTeX

@article{101c1e761e094526be443c907491964b,
title = "Double yttrium thiosilicates AYSiS4 (A = Rb, Cs): synthesis, structure, optical properties",
abstract = "By the high-temperature synthesis new double yttrium thiosilicates AYSiS4, A = Rb, Cs are obtained. The compounds crystallize in the orthorhombic system (space group P212121) with the following parameters: a = 6.3381(4) {\AA}, b = 6.5961(4) {\AA}, c = 16.8868(12) {\AA} for RbYSiS4 and a = 6.3303(4) {\AA}, b = 6.6593(5) {\AA}, c = 17.5795(13) {\AA} for CsYSiS4. The compound with rubidium is rapidly hydrolyzed by water; the compound with cesium is stable in dry air. For CsYSiS4 the band gap estimated by diffuse reflectance is 3.8 eV. The photoluminescence spectrum has a broad band in the visible region with the maximum at λ = 492 nm (green region). The lifetimes are τ1 = 5.25 µs and τ2 = 0.26 µs with the quantum yield of ",
keywords = "crystal structure, photoluminescence, thiosilicate, yttrium",
author = "Tarasenko, {M. S.} and Duritsyn, {R. V.} and Potapov, {D. A.} and Kuratieva, {N. V.} and Ryadun, {A. A.} and Naumov, {N. G.}",
note = "FUNDING: The work was supported by the Ministry of Science and Higher Education of the Russian Federation (projects Nos. 121031700315-2 and 121031700313-8). ",
year = "2022",
month = dec,
day = "1",
doi = "10.1134/S0022476622120101",
language = "English",
volume = "63",
pages = "1988--1996",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "12",

}

RIS

TY - JOUR

T1 - Double yttrium thiosilicates AYSiS4 (A = Rb, Cs): synthesis, structure, optical properties

AU - Tarasenko, M. S.

AU - Duritsyn, R. V.

AU - Potapov, D. A.

AU - Kuratieva, N. V.

AU - Ryadun, A. A.

AU - Naumov, N. G.

N1 - FUNDING: The work was supported by the Ministry of Science and Higher Education of the Russian Federation (projects Nos. 121031700315-2 and 121031700313-8).

PY - 2022/12/1

Y1 - 2022/12/1

N2 - By the high-temperature synthesis new double yttrium thiosilicates AYSiS4, A = Rb, Cs are obtained. The compounds crystallize in the orthorhombic system (space group P212121) with the following parameters: a = 6.3381(4) Å, b = 6.5961(4) Å, c = 16.8868(12) Å for RbYSiS4 and a = 6.3303(4) Å, b = 6.6593(5) Å, c = 17.5795(13) Å for CsYSiS4. The compound with rubidium is rapidly hydrolyzed by water; the compound with cesium is stable in dry air. For CsYSiS4 the band gap estimated by diffuse reflectance is 3.8 eV. The photoluminescence spectrum has a broad band in the visible region with the maximum at λ = 492 nm (green region). The lifetimes are τ1 = 5.25 µs and τ2 = 0.26 µs with the quantum yield of

AB - By the high-temperature synthesis new double yttrium thiosilicates AYSiS4, A = Rb, Cs are obtained. The compounds crystallize in the orthorhombic system (space group P212121) with the following parameters: a = 6.3381(4) Å, b = 6.5961(4) Å, c = 16.8868(12) Å for RbYSiS4 and a = 6.3303(4) Å, b = 6.6593(5) Å, c = 17.5795(13) Å for CsYSiS4. The compound with rubidium is rapidly hydrolyzed by water; the compound with cesium is stable in dry air. For CsYSiS4 the band gap estimated by diffuse reflectance is 3.8 eV. The photoluminescence spectrum has a broad band in the visible region with the maximum at λ = 492 nm (green region). The lifetimes are τ1 = 5.25 µs and τ2 = 0.26 µs with the quantum yield of

KW - crystal structure

KW - photoluminescence

KW - thiosilicate

KW - yttrium

UR - https://www.scopus.com/inward/record.url?eid=2-s2.0-85145360604&partnerID=40&md5=81473ad72098fea498dcafcd9b3fe9b0

UR - https://www.mendeley.com/catalogue/b29a8f28-28e7-3ebf-8935-9c5a6194a09c/

U2 - 10.1134/S0022476622120101

DO - 10.1134/S0022476622120101

M3 - Article

VL - 63

SP - 1988

EP - 1996

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 12

ER -

ID: 44625920