Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe2)5 with CS2

Standard

Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe₂)₅ with CS₂. / Petrov, P. A.; Rogachev, A. V.; El’tsov, I. V. и др.

в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 47, № 10, 10.2021, стр. 657-663.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Petrov, PA, Rogachev, AV, El’tsov, IV, Sukhikh, TS, Laricheva, YA, Abramov, PA & Sokolov, MN 2021, 'Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe₂)₅ with CS₂', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том. 47, № 10, стр. 657-663. https://doi.org/10.1134/S1070328421100055

APA

Petrov, P. A., Rogachev, A. V., El’tsov, I. V., Sukhikh, T. S., Laricheva, Y. A., Abramov, P. A., & Sokolov, M. N. (2021). Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe₂)₅ with CS₂. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 47(10), 657-663. https://doi.org/10.1134/S1070328421100055

Vancouver

Petrov PA, Rogachev AV, El’tsov IV, Sukhikh TS, Laricheva YA, Abramov PA и др. Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe₂)₅ with CS₂. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021 окт.;47(10):657-663. doi: 10.1134/S1070328421100055

Author

Petrov, P. A. ; Rogachev, A. V. ; El’tsov, I. V. и др. / Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe₂)₅ with CS₂. в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021 ; Том 47, № 10. стр. 657-663.

BibTeX

@article{99585618f64a4cc1a3ce35d65c19c051,

title = "Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe2)5 with CS2",

abstract = "The reaction of Ta(NMe2)5 with CS2 resulted in the isolation of azametallacyclopropane complex [Ta(MeDtc)3(η2-CH2NMe)] (I, MeDtc = dimethyldithiocarbamate), which was characterized by X-ray diffraction in the solvent-free form and as a toluene solvate (CCDC nos. 2005837 (I), 2049693 (I∙0.5C7H8)) and by NMR spectroscopy and DFT calculations.",

keywords = "amides, dithiocarbamates, tantalum, X-ray diffraction",

author = "Petrov, {P. A.} and Rogachev, {A. V.} and El{\textquoteright}tsov, {I. V.} and Sukhikh, {T. S.} and Laricheva, {Yu A.} and Abramov, {P. A.} and Sokolov, {M. N.}",

note = "Funding Information: This study was supported by the Russian Academy of Sciences (budget program V55.1.1). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",

year = "2021",

month = oct,

doi = "10.1134/S1070328421100055",

language = "English",

volume = "47",

pages = "657--663",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "10",

}

RIS

TY - JOUR

T1 - Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe2)5 with CS2

AU - Petrov, P. A.

AU - Rogachev, A. V.

AU - El’tsov, I. V.

AU - Sukhikh, T. S.

AU - Laricheva, Yu A.

AU - Abramov, P. A.

AU - Sokolov, M. N.

PY - 2021/10

Y1 - 2021/10

N2 - The reaction of Ta(NMe2)5 with CS2 resulted in the isolation of azametallacyclopropane complex [Ta(MeDtc)3(η2-CH2NMe)] (I, MeDtc = dimethyldithiocarbamate), which was characterized by X-ray diffraction in the solvent-free form and as a toluene solvate (CCDC nos. 2005837 (I), 2049693 (I∙0.5C7H8)) and by NMR spectroscopy and DFT calculations.

AB - The reaction of Ta(NMe2)5 with CS2 resulted in the isolation of azametallacyclopropane complex [Ta(MeDtc)3(η2-CH2NMe)] (I, MeDtc = dimethyldithiocarbamate), which was characterized by X-ray diffraction in the solvent-free form and as a toluene solvate (CCDC nos. 2005837 (I), 2049693 (I∙0.5C7H8)) and by NMR spectroscopy and DFT calculations.

KW - amides

KW - dithiocarbamates

KW - tantalum

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=85119381674&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/7e78682b-937a-3b01-93a5-e083a14f5dea/

U2 - 10.1134/S1070328421100055

DO - 10.1134/S1070328421100055

M3 - Article

AN - SCOPUS:85119381674

VL - 47

SP - 657

EP - 663

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 10

ER -

ID: 34690809