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Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe2)5 with CS2. / Petrov, P. A.; Rogachev, A. V.; El’tsov, I. V. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 47, No. 10, 10.2021, p. 657-663.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA, Rogachev, AV, El’tsov, IV, Sukhikh, TS, Laricheva, YA, Abramov, PA & Sokolov, MN 2021, 'Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe2)5 with CS2', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 10, pp. 657-663. https://doi.org/10.1134/S1070328421100055

APA

Petrov, P. A., Rogachev, A. V., El’tsov, I. V., Sukhikh, T. S., Laricheva, Y. A., Abramov, P. A., & Sokolov, M. N. (2021). Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe2)5 with CS2. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 47(10), 657-663. https://doi.org/10.1134/S1070328421100055

Vancouver

Petrov PA, Rogachev AV, El’tsov IV, Sukhikh TS, Laricheva YA, Abramov PA et al. Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe2)5 with CS2. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021 Oct;47(10):657-663. doi: 10.1134/S1070328421100055

Author

Petrov, P. A. ; Rogachev, A. V. ; El’tsov, I. V. et al. / Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe2)5 with CS2. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021 ; Vol. 47, No. 10. pp. 657-663.

BibTeX

@article{99585618f64a4cc1a3ce35d65c19c051,
title = "Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe2)5 with CS2",
abstract = "The reaction of Ta(NMe2)5 with CS2 resulted in the isolation of azametallacyclopropane complex [Ta(MeDtc)3(η2-CH2NMe)] (I, MeDtc = dimethyldithiocarbamate), which was characterized by X-ray diffraction in the solvent-free form and as a toluene solvate (CCDC nos. 2005837 (I), 2049693 (I∙0.5C7H8)) and by NMR spectroscopy and DFT calculations.",
keywords = "amides, dithiocarbamates, tantalum, X-ray diffraction",
author = "Petrov, {P. A.} and Rogachev, {A. V.} and El{\textquoteright}tsov, {I. V.} and Sukhikh, {T. S.} and Laricheva, {Yu A.} and Abramov, {P. A.} and Sokolov, {M. N.}",
note = "Funding Information: This study was supported by the Russian Academy of Sciences (budget program V55.1.1). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",
year = "2021",
month = oct,
doi = "10.1134/S1070328421100055",
language = "English",
volume = "47",
pages = "657--663",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "10",

}

RIS

TY - JOUR

T1 - Cyclometallation of the Dimethylamide Ligand in the Reaction of Ta(NMe2)5 with CS2

AU - Petrov, P. A.

AU - Rogachev, A. V.

AU - El’tsov, I. V.

AU - Sukhikh, T. S.

AU - Laricheva, Yu A.

AU - Abramov, P. A.

AU - Sokolov, M. N.

N1 - Funding Information: This study was supported by the Russian Academy of Sciences (budget program V55.1.1). Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/10

Y1 - 2021/10

N2 - The reaction of Ta(NMe2)5 with CS2 resulted in the isolation of azametallacyclopropane complex [Ta(MeDtc)3(η2-CH2NMe)] (I, MeDtc = dimethyldithiocarbamate), which was characterized by X-ray diffraction in the solvent-free form and as a toluene solvate (CCDC nos. 2005837 (I), 2049693 (I∙0.5C7H8)) and by NMR spectroscopy and DFT calculations.

AB - The reaction of Ta(NMe2)5 with CS2 resulted in the isolation of azametallacyclopropane complex [Ta(MeDtc)3(η2-CH2NMe)] (I, MeDtc = dimethyldithiocarbamate), which was characterized by X-ray diffraction in the solvent-free form and as a toluene solvate (CCDC nos. 2005837 (I), 2049693 (I∙0.5C7H8)) and by NMR spectroscopy and DFT calculations.

KW - amides

KW - dithiocarbamates

KW - tantalum

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=85119381674&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/7e78682b-937a-3b01-93a5-e083a14f5dea/

U2 - 10.1134/S1070328421100055

DO - 10.1134/S1070328421100055

M3 - Article

AN - SCOPUS:85119381674

VL - 47

SP - 657

EP - 663

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 10

ER -

ID: 34690809