Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Crystal structure of the seven-electron molybdenum cluster [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O. / Petrov, P. A.; Sosnin, G. A.; Naumov, D. Yu и др.
в: Journal of Structural Chemistry, Том 56, № 4, 30.07.2015, стр. 765-768.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Crystal structure of the seven-electron molybdenum cluster [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O
AU - Petrov, P. A.
AU - Sosnin, G. A.
AU - Naumov, D. Yu
AU - Konchenko, S. N.
PY - 2015/7/30
Y1 - 2015/7/30
N2 - The seven-electron neutral cluster complex [Mo3S4(dppe)3Cl3] (dppe = Ph2PCH2CH2PPh2) is obtained by the reduction of the [Mo3S4(dppe)3Cl3]Cl cluster with gallium metal. The molecular and crystal structure of [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O solvate is determined by single crystal XRD. The crystallographic data are as follows: monoclinic crystal symmetry, space group C2/c, a = 41.1775(16) Å, b = 17.7178(7) Å, c = 28.9609(9) Å, β = 110.363(1)°, V = 19808.7(13) Å3, Z = 8, d calc = 1.384 g/cm3.
AB - The seven-electron neutral cluster complex [Mo3S4(dppe)3Cl3] (dppe = Ph2PCH2CH2PPh2) is obtained by the reduction of the [Mo3S4(dppe)3Cl3]Cl cluster with gallium metal. The molecular and crystal structure of [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O solvate is determined by single crystal XRD. The crystallographic data are as follows: monoclinic crystal symmetry, space group C2/c, a = 41.1775(16) Å, b = 17.7178(7) Å, c = 28.9609(9) Å, β = 110.363(1)°, V = 19808.7(13) Å3, Z = 8, d calc = 1.384 g/cm3.
KW - cluster complexes
KW - molybdenum
KW - single crystal X-ray diffraction study
KW - sulfur
UR - http://www.scopus.com/inward/record.url?scp=84942518556&partnerID=8YFLogxK
U2 - 10.1134/S002247661504023X
DO - 10.1134/S002247661504023X
M3 - Article
AN - SCOPUS:84942518556
VL - 56
SP - 765
EP - 768
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 4
ER -
ID: 25415283