Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Cristal structures of polynuclear antimony bromidecomplexes (Et(n-Pr)3N)3[Sb3Br12] and (2,2′-bipyH)4[Sb4Br20]. / Petrov, M. D.; Sokolov, M. N.; Fedin, V. P. и др.
в: Journal of Structural Chemistry, Том 61, № 11, 11.2020, стр. 1794-1799.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Cristal structures of polynuclear antimony bromidecomplexes (Et(n-Pr)3N)3[Sb3Br12] and (2,2′-bipyH)4[Sb4Br20]
AU - Petrov, M. D.
AU - Sokolov, M. N.
AU - Fedin, V. P.
AU - Adonin, S. A.
N1 - Funding Information: The work was supported by the Russian Science Foundation (Project No. 18-73-10040). Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/11
Y1 - 2020/11
N2 - Trinuclear (Et(n-Pr)3N)3[Sb3Br12] (1) and tetranuclear (2,2′-bipyH)4[Sb4Br20] (2) bromoantimonates(III) are obtained by the reaction of solutions of bromides of the respective organic cations and Sb2O3 in HBr. The structures of 1 and 2 are studied by single crystal XRD. The [Sb3Br12]3– (1) anions belong to a previously unknown structure type of halide Sb(III) complexes.
AB - Trinuclear (Et(n-Pr)3N)3[Sb3Br12] (1) and tetranuclear (2,2′-bipyH)4[Sb4Br20] (2) bromoantimonates(III) are obtained by the reaction of solutions of bromides of the respective organic cations and Sb2O3 in HBr. The structures of 1 and 2 are studied by single crystal XRD. The [Sb3Br12]3– (1) anions belong to a previously unknown structure type of halide Sb(III) complexes.
KW - antimony
KW - crystal structure
KW - halide complexes
KW - polynuclear complexes
KW - IODOBISMUTHATE COMPLEX
KW - BISMUTH COMPLEXES
KW - HALIDE-COMPLEXES
KW - THERMOCHROMIC PROPERTIES
KW - METHYLAMMONIUM LEAD
KW - FERROELECTRIC BIS(IMIDAZOLIUM) PENTACHLOROANTIMONATE(III)
KW - PHASE-TRANSITION
KW - CENTER-DOT
KW - PEROVSKITE
KW - 2,2'-BIPYRIDINIUM
UR - http://www.scopus.com/inward/record.url?scp=85097978942&partnerID=8YFLogxK
U2 - 10.1134/S0022476620110128
DO - 10.1134/S0022476620110128
M3 - Article
AN - SCOPUS:85097978942
VL - 61
SP - 1794
EP - 1799
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 11
ER -
ID: 27330161