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Cristal structures of polynuclear antimony bromidecomplexes (Et(n-Pr)3N)3[Sb3Br12] and (2,2′-bipyH)4[Sb4Br20]. / Petrov, M. D.; Sokolov, M. N.; Fedin, V. P. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 11, 11.2020, p. 1794-1799.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, MD, Sokolov, MN, Fedin, VP & Adonin, SA 2020, 'Cristal structures of polynuclear antimony bromidecomplexes (Et(n-Pr)3N)3[Sb3Br12] and (2,2′-bipyH)4[Sb4Br20]', Journal of Structural Chemistry, vol. 61, no. 11, pp. 1794-1799. https://doi.org/10.1134/S0022476620110128

APA

Petrov, M. D., Sokolov, M. N., Fedin, V. P., & Adonin, S. A. (2020). Cristal structures of polynuclear antimony bromidecomplexes (Et(n-Pr)3N)3[Sb3Br12] and (2,2′-bipyH)4[Sb4Br20]. Journal of Structural Chemistry, 61(11), 1794-1799. https://doi.org/10.1134/S0022476620110128

Vancouver

Petrov MD, Sokolov MN, Fedin VP, Adonin SA. Cristal structures of polynuclear antimony bromidecomplexes (Et(n-Pr)3N)3[Sb3Br12] and (2,2′-bipyH)4[Sb4Br20]. Journal of Structural Chemistry. 2020 Nov;61(11):1794-1799. doi: 10.1134/S0022476620110128

Author

Petrov, M. D. ; Sokolov, M. N. ; Fedin, V. P. et al. / Cristal structures of polynuclear antimony bromidecomplexes (Et(n-Pr)3N)3[Sb3Br12] and (2,2′-bipyH)4[Sb4Br20]. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 11. pp. 1794-1799.

BibTeX

@article{67df32be86f942a0920b87e94b8a24e3,
title = "Cristal structures of polynuclear antimony bromidecomplexes (Et(n-Pr)3N)3[Sb3Br12] and (2,2′-bipyH)4[Sb4Br20]",
abstract = "Trinuclear (Et(n-Pr)3N)3[Sb3Br12] (1) and tetranuclear (2,2′-bipyH)4[Sb4Br20] (2) bromoantimonates(III) are obtained by the reaction of solutions of bromides of the respective organic cations and Sb2O3 in HBr. The structures of 1 and 2 are studied by single crystal XRD. The [Sb3Br12]3– (1) anions belong to a previously unknown structure type of halide Sb(III) complexes.",
keywords = "antimony, crystal structure, halide complexes, polynuclear complexes, IODOBISMUTHATE COMPLEX, BISMUTH COMPLEXES, HALIDE-COMPLEXES, THERMOCHROMIC PROPERTIES, METHYLAMMONIUM LEAD, FERROELECTRIC BIS(IMIDAZOLIUM) PENTACHLOROANTIMONATE(III), PHASE-TRANSITION, CENTER-DOT, PEROVSKITE, 2,2'-BIPYRIDINIUM",
author = "Petrov, {M. D.} and Sokolov, {M. N.} and Fedin, {V. P.} and Adonin, {S. A.}",
note = "Funding Information: The work was supported by the Russian Science Foundation (Project No. 18-73-10040). Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = nov,
doi = "10.1134/S0022476620110128",
language = "English",
volume = "61",
pages = "1794--1799",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "11",

}

RIS

TY - JOUR

T1 - Cristal structures of polynuclear antimony bromidecomplexes (Et(n-Pr)3N)3[Sb3Br12] and (2,2′-bipyH)4[Sb4Br20]

AU - Petrov, M. D.

AU - Sokolov, M. N.

AU - Fedin, V. P.

AU - Adonin, S. A.

N1 - Funding Information: The work was supported by the Russian Science Foundation (Project No. 18-73-10040). Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/11

Y1 - 2020/11

N2 - Trinuclear (Et(n-Pr)3N)3[Sb3Br12] (1) and tetranuclear (2,2′-bipyH)4[Sb4Br20] (2) bromoantimonates(III) are obtained by the reaction of solutions of bromides of the respective organic cations and Sb2O3 in HBr. The structures of 1 and 2 are studied by single crystal XRD. The [Sb3Br12]3– (1) anions belong to a previously unknown structure type of halide Sb(III) complexes.

AB - Trinuclear (Et(n-Pr)3N)3[Sb3Br12] (1) and tetranuclear (2,2′-bipyH)4[Sb4Br20] (2) bromoantimonates(III) are obtained by the reaction of solutions of bromides of the respective organic cations and Sb2O3 in HBr. The structures of 1 and 2 are studied by single crystal XRD. The [Sb3Br12]3– (1) anions belong to a previously unknown structure type of halide Sb(III) complexes.

KW - antimony

KW - crystal structure

KW - halide complexes

KW - polynuclear complexes

KW - IODOBISMUTHATE COMPLEX

KW - BISMUTH COMPLEXES

KW - HALIDE-COMPLEXES

KW - THERMOCHROMIC PROPERTIES

KW - METHYLAMMONIUM LEAD

KW - FERROELECTRIC BIS(IMIDAZOLIUM) PENTACHLOROANTIMONATE(III)

KW - PHASE-TRANSITION

KW - CENTER-DOT

KW - PEROVSKITE

KW - 2,2'-BIPYRIDINIUM

UR - http://www.scopus.com/inward/record.url?scp=85097978942&partnerID=8YFLogxK

U2 - 10.1134/S0022476620110128

DO - 10.1134/S0022476620110128

M3 - Article

AN - SCOPUS:85097978942

VL - 61

SP - 1794

EP - 1799

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 11

ER -

ID: 27330161