Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP). / Audran, Gérard; Bagryanskaya, Elena; Edeleva, Mariya и др.
в: Australian Journal of Chemistry, Том 71, № 5, 01.01.2018, стр. 334-340.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP)
AU - Audran, Gérard
AU - Bagryanskaya, Elena
AU - Edeleva, Mariya
AU - Marque, Sylvain R.A.
AU - Parkhomenko, Dmitriy
AU - Tretyakov, Evgeny
AU - Zhivetyeva, Svetlana
PY - 2018/1/1
Y1 - 2018/1/1
N2 - Preparation of materials by nitroxide-mediated polymerization (NMP) is well known nowadays. To increase the possible usefulness of NMP for the production of hybrid materials or polymer-decorated complexes, coordination-initiated NMP (CI-NMP) was developed and investigated here. CI-NMP was exemplified using the instantaneous and spontaneous reaction of alkoxyamines carrying a pyridyl moiety on the alkyl group and the Zn(hfac)2 (hfac: hexafluoroacetylacetonate) complex as a metal centre. NMP of styrene and n-butyl acrylate was carried out with either previously or in situ-prepared complexes. Both approaches afforded NMP of the same quality. The positive influence of metal centre coordination is highlighted by efficient NMP at 90°C.
AB - Preparation of materials by nitroxide-mediated polymerization (NMP) is well known nowadays. To increase the possible usefulness of NMP for the production of hybrid materials or polymer-decorated complexes, coordination-initiated NMP (CI-NMP) was developed and investigated here. CI-NMP was exemplified using the instantaneous and spontaneous reaction of alkoxyamines carrying a pyridyl moiety on the alkyl group and the Zn(hfac)2 (hfac: hexafluoroacetylacetonate) complex as a metal centre. NMP of styrene and n-butyl acrylate was carried out with either previously or in situ-prepared complexes. Both approaches afforded NMP of the same quality. The positive influence of metal centre coordination is highlighted by efficient NMP at 90°C.
KW - ON BOND HOMOLYSIS
KW - EMITTING MATERIALS
KW - ALKOXYAMINES
KW - COMPLEXES
UR - http://www.scopus.com/inward/record.url?scp=85047533641&partnerID=8YFLogxK
U2 - 10.1071/CH17570
DO - 10.1071/CH17570
M3 - Article
AN - SCOPUS:85047533641
VL - 71
SP - 334
EP - 340
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
SN - 0004-9425
IS - 5
ER -
ID: 13632322