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Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP). / Audran, Gérard; Bagryanskaya, Elena; Edeleva, Mariya et al.

In: Australian Journal of Chemistry, Vol. 71, No. 5, 01.01.2018, p. 334-340.

Research output: Contribution to journal › Article › peer-review

Harvard

Audran, G, Bagryanskaya, E, Edeleva, M, Marque, SRA, Parkhomenko, D, Tretyakov, E & Zhivetyeva, S 2018, 'Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP)', Australian Journal of Chemistry, vol. 71, no. 5, pp. 334-340. https://doi.org/10.1071/CH17570

APA

Audran, G., Bagryanskaya, E., Edeleva, M., Marque, S. R. A., Parkhomenko, D., Tretyakov, E., & Zhivetyeva, S. (2018). Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP). Australian Journal of Chemistry, 71(5), 334-340. https://doi.org/10.1071/CH17570

Vancouver

Audran G, Bagryanskaya E, Edeleva M, Marque SRA, Parkhomenko D, Tretyakov E et al. Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP). Australian Journal of Chemistry. 2018 Jan 1;71(5):334-340. doi: 10.1071/CH17570

Author

Audran, Gérard ; Bagryanskaya, Elena ; Edeleva, Mariya et al. / Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP). In: Australian Journal of Chemistry. 2018 ; Vol. 71, No. 5. pp. 334-340.

BibTeX

@article{9c618f3330924e55a09c580fd77aa943,
title = "Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP)",
abstract = "Preparation of materials by nitroxide-mediated polymerization (NMP) is well known nowadays. To increase the possible usefulness of NMP for the production of hybrid materials or polymer-decorated complexes, coordination-initiated NMP (CI-NMP) was developed and investigated here. CI-NMP was exemplified using the instantaneous and spontaneous reaction of alkoxyamines carrying a pyridyl moiety on the alkyl group and the Zn(hfac)2 (hfac: hexafluoroacetylacetonate) complex as a metal centre. NMP of styrene and n-butyl acrylate was carried out with either previously or in situ-prepared complexes. Both approaches afforded NMP of the same quality. The positive influence of metal centre coordination is highlighted by efficient NMP at 90°C.",
keywords = "ON BOND HOMOLYSIS, EMITTING MATERIALS, ALKOXYAMINES, COMPLEXES",
author = "G{\'e}rard Audran and Elena Bagryanskaya and Mariya Edeleva and Marque, {Sylvain R.A.} and Dmitriy Parkhomenko and Evgeny Tretyakov and Svetlana Zhivetyeva",
year = "2018",
month = jan,
day = "1",
doi = "10.1071/CH17570",
language = "English",
volume = "71",
pages = "334--340",
journal = "Australian Journal of Chemistry",
issn = "0004-9425",
publisher = "CSIRO",
number = "5",

}

RIS

TY - JOUR

T1 - Coordination-Initiated Nitroxide-Mediated Polymerization (CI-NMP)

AU - Audran, Gérard

AU - Bagryanskaya, Elena

AU - Edeleva, Mariya

AU - Marque, Sylvain R.A.

AU - Parkhomenko, Dmitriy

AU - Tretyakov, Evgeny

AU - Zhivetyeva, Svetlana

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Preparation of materials by nitroxide-mediated polymerization (NMP) is well known nowadays. To increase the possible usefulness of NMP for the production of hybrid materials or polymer-decorated complexes, coordination-initiated NMP (CI-NMP) was developed and investigated here. CI-NMP was exemplified using the instantaneous and spontaneous reaction of alkoxyamines carrying a pyridyl moiety on the alkyl group and the Zn(hfac)2 (hfac: hexafluoroacetylacetonate) complex as a metal centre. NMP of styrene and n-butyl acrylate was carried out with either previously or in situ-prepared complexes. Both approaches afforded NMP of the same quality. The positive influence of metal centre coordination is highlighted by efficient NMP at 90°C.

AB - Preparation of materials by nitroxide-mediated polymerization (NMP) is well known nowadays. To increase the possible usefulness of NMP for the production of hybrid materials or polymer-decorated complexes, coordination-initiated NMP (CI-NMP) was developed and investigated here. CI-NMP was exemplified using the instantaneous and spontaneous reaction of alkoxyamines carrying a pyridyl moiety on the alkyl group and the Zn(hfac)2 (hfac: hexafluoroacetylacetonate) complex as a metal centre. NMP of styrene and n-butyl acrylate was carried out with either previously or in situ-prepared complexes. Both approaches afforded NMP of the same quality. The positive influence of metal centre coordination is highlighted by efficient NMP at 90°C.

KW - ON BOND HOMOLYSIS

KW - EMITTING MATERIALS

KW - ALKOXYAMINES

KW - COMPLEXES

UR - http://www.scopus.com/inward/record.url?scp=85047533641&partnerID=8YFLogxK

U2 - 10.1071/CH17570

DO - 10.1071/CH17570

M3 - Article

AN - SCOPUS:85047533641

VL - 71

SP - 334

EP - 340

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

SN - 0004-9425

IS - 5

ER -

ID: 13632322