TY - JOUR

T1 - Coordination Polymers of Scandium(III) and Thiophenedicarboxylic Acid

AU - Lysova, A. A.

AU - Dubskikh, V. A.

AU - Abasheeva, K. D.

AU - Vasileva, A. A.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research and Government of the Novosibirsk oblast, project no. 20-43-540010. Publisher Copyright: © 2021, The Author(s).

PY - 2021/9

Y1 - 2021/9

N2 - Three new metal−organic frameworks based on scandium(III) cations and 2,5-thiophenedicarboxylic acid (H2Tdc) are synthesized: [Sc(Tdc)(OH)]·1.2DMF (I), [Sc(Tdc)(OH)]·2/3DMF (II), and (Me2NH2)[Sc3(Tdc)4(OH)2]·DMF (III) (DMF is N,N-dimethylformamide). The structures of the compounds are determined by single-crystal X-ray structure analysis (CIF file CCDC nos. 2067819 (I), 2067820 (II), and 2067821 (III)). The chemical and phase purity of compound I is proved by elemental analysis, thermogravimetry, X-ray diffraction analysis, and IR spectroscopy.

AB - Three new metal−organic frameworks based on scandium(III) cations and 2,5-thiophenedicarboxylic acid (H2Tdc) are synthesized: [Sc(Tdc)(OH)]·1.2DMF (I), [Sc(Tdc)(OH)]·2/3DMF (II), and (Me2NH2)[Sc3(Tdc)4(OH)2]·DMF (III) (DMF is N,N-dimethylformamide). The structures of the compounds are determined by single-crystal X-ray structure analysis (CIF file CCDC nos. 2067819 (I), 2067820 (II), and 2067821 (III)). The chemical and phase purity of compound I is proved by elemental analysis, thermogravimetry, X-ray diffraction analysis, and IR spectroscopy.

KW - 2,5-thiophenedicarboxylic acid

KW - metal−organic frameworks

KW - scandium(III)

UR - http://www.scopus.com/inward/record.url?scp=85114723354&partnerID=8YFLogxK

U2 - 10.1134/S1070328421090062

DO - 10.1134/S1070328421090062

M3 - Article

AN - SCOPUS:85114723354

VL - 47

SP - 593

EP - 600

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 9

ER -