Research output: Contribution to journal › Article › peer-review
Coordination Polymers of Scandium(III) and Thiophenedicarboxylic Acid. / Lysova, A. A.; Dubskikh, V. A.; Abasheeva, K. D. et al.
In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 47, No. 9, 09.2021, p. 593-600.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Coordination Polymers of Scandium(III) and Thiophenedicarboxylic Acid
AU - Lysova, A. A.
AU - Dubskikh, V. A.
AU - Abasheeva, K. D.
AU - Vasileva, A. A.
AU - Samsonenko, D. G.
AU - Dybtsev, D. N.
N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research and Government of the Novosibirsk oblast, project no. 20-43-540010. Publisher Copyright: © 2021, The Author(s).
PY - 2021/9
Y1 - 2021/9
N2 - Three new metal−organic frameworks based on scandium(III) cations and 2,5-thiophenedicarboxylic acid (H2Tdc) are synthesized: [Sc(Tdc)(OH)]·1.2DMF (I), [Sc(Tdc)(OH)]·2/3DMF (II), and (Me2NH2)[Sc3(Tdc)4(OH)2]·DMF (III) (DMF is N,N-dimethylformamide). The structures of the compounds are determined by single-crystal X-ray structure analysis (CIF file CCDC nos. 2067819 (I), 2067820 (II), and 2067821 (III)). The chemical and phase purity of compound I is proved by elemental analysis, thermogravimetry, X-ray diffraction analysis, and IR spectroscopy.
AB - Three new metal−organic frameworks based on scandium(III) cations and 2,5-thiophenedicarboxylic acid (H2Tdc) are synthesized: [Sc(Tdc)(OH)]·1.2DMF (I), [Sc(Tdc)(OH)]·2/3DMF (II), and (Me2NH2)[Sc3(Tdc)4(OH)2]·DMF (III) (DMF is N,N-dimethylformamide). The structures of the compounds are determined by single-crystal X-ray structure analysis (CIF file CCDC nos. 2067819 (I), 2067820 (II), and 2067821 (III)). The chemical and phase purity of compound I is proved by elemental analysis, thermogravimetry, X-ray diffraction analysis, and IR spectroscopy.
KW - 2,5-thiophenedicarboxylic acid
KW - metal−organic frameworks
KW - scandium(III)
UR - http://www.scopus.com/inward/record.url?scp=85114723354&partnerID=8YFLogxK
U2 - 10.1134/S1070328421090062
DO - 10.1134/S1070328421090062
M3 - Article
AN - SCOPUS:85114723354
VL - 47
SP - 593
EP - 600
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 9
ER -
ID: 34190176